FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time
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Sodium carbonate was mechanically activated for 7 minutes in a vibro mill at a frequency of 3000 oscillations per minute. Activated samples were stored in the air at room conditions for 31 days. To monitor the kinetics of the transformation process of sodium carbonate to bicarbonate, Fourier-transform infrared (FTIR) spectroscopy analysis was used and was performed as a function of relaxation time for characteristic groups observed: CO3 2–, HCO3 – and OH–. The obtained results provided kinetics parameters for the transformation of carbonate into bicarbonate as a result of chemisorption of moisture and carbon dioxide from the atmosphere.
Keywords:
mechanical activation / sodium carbonate / mechanochemical transformation / FTIRSource:
Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia, 2021, 201-202Publisher:
- University of Belgrade, Faculty of Mechanical Engineering
- Serbian Tribology Society
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200023 (Institute of Technology of Nuclear and Other Mineral Row Materials - ITNMS, Belgrade) (RS-200023)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200131 (University of Belgrade, Technical Faculty, Bor) (RS-200131)
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IHTMTY - CONF AU - Đorđević, Nataša AU - Vlahović, Milica AU - Mihajlović, Slavica AU - Martinović, Sanja AU - Vušović, Nenad PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5979 AB - Sodium carbonate was mechanically activated for 7 minutes in a vibro mill at a frequency of 3000 oscillations per minute. Activated samples were stored in the air at room conditions for 31 days. To monitor the kinetics of the transformation process of sodium carbonate to bicarbonate, Fourier-transform infrared (FTIR) spectroscopy analysis was used and was performed as a function of relaxation time for characteristic groups observed: CO3 2–, HCO3 – and OH–. The obtained results provided kinetics parameters for the transformation of carbonate into bicarbonate as a result of chemisorption of moisture and carbon dioxide from the atmosphere. PB - University of Belgrade, Faculty of Mechanical Engineering PB - Serbian Tribology Society C3 - Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia T1 - FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time SP - 201 EP - 202 UR - https://hdl.handle.net/21.15107/rcub_cer_5979 ER -
@conference{ author = "Đorđević, Nataša and Vlahović, Milica and Mihajlović, Slavica and Martinović, Sanja and Vušović, Nenad", year = "2021", abstract = "Sodium carbonate was mechanically activated for 7 minutes in a vibro mill at a frequency of 3000 oscillations per minute. Activated samples were stored in the air at room conditions for 31 days. To monitor the kinetics of the transformation process of sodium carbonate to bicarbonate, Fourier-transform infrared (FTIR) spectroscopy analysis was used and was performed as a function of relaxation time for characteristic groups observed: CO3 2–, HCO3 – and OH–. The obtained results provided kinetics parameters for the transformation of carbonate into bicarbonate as a result of chemisorption of moisture and carbon dioxide from the atmosphere.", publisher = "University of Belgrade, Faculty of Mechanical Engineering, Serbian Tribology Society", journal = "Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia", title = "FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time", pages = "201-202", url = "https://hdl.handle.net/21.15107/rcub_cer_5979" }
Đorđević, N., Vlahović, M., Mihajlović, S., Martinović, S.,& Vušović, N.. (2021). FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time. in Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia University of Belgrade, Faculty of Mechanical Engineering., 201-202. https://hdl.handle.net/21.15107/rcub_cer_5979
Đorđević N, Vlahović M, Mihajlović S, Martinović S, Vušović N. FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time. in Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia. 2021;:201-202. https://hdl.handle.net/21.15107/rcub_cer_5979 .
Đorđević, Nataša, Vlahović, Milica, Mihajlović, Slavica, Martinović, Sanja, Vušović, Nenad, "FTIR spectroscopy analysis of mechanochemically activated Na2CO3 during relaxation time" in Proceedings - 10th International Conference on Tribology–BALKANTRIB'20, 20 – 22 May 2021, Belgrade, Serbia (2021):201-202, https://hdl.handle.net/21.15107/rcub_cer_5979 .