Aluminium electrodeposition from chloroaluminate melts
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Electrodeposited aluminium from a low temperature equimolar chloroaluminate melt onto a planar aluminium cathode was investigated. Experimental techniques used were linear sweep voltammetry, potential step and analytical techniques were SEM and EDS. Results show that a relatively adherent and compact aluminium deposit featuring high surface area can be successfully electrodeposited from melts at 200◦C. Electrodeposition done under potentiostatic control indicates that aluminium deposits are made up of extremely small particles of irregular shape and that a moderate increase in applied overpotential leads to decrease in crystallite down to nanoparticle size. Surface morphology of the Al deposit can be optimized by adjusting electrodeposition parameters.
Keywords:
batteries / aluminium electrodes / aluminium deposition / chloroaluminate meltSource:
Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia, 2017, 237-240Publisher:
- University of Belgrade - Technical Faculty in Bor
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IHTMTY - CONF AU - Cvetković, Vesna S. AU - Vukićević, Nataša AU - Stevanović, Jasmina S. AU - Jovićević, Jovan N. PY - 2017 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5870 AB - Electrodeposited aluminium from a low temperature equimolar chloroaluminate melt onto a planar aluminium cathode was investigated. Experimental techniques used were linear sweep voltammetry, potential step and analytical techniques were SEM and EDS. Results show that a relatively adherent and compact aluminium deposit featuring high surface area can be successfully electrodeposited from melts at 200◦C. Electrodeposition done under potentiostatic control indicates that aluminium deposits are made up of extremely small particles of irregular shape and that a moderate increase in applied overpotential leads to decrease in crystallite down to nanoparticle size. Surface morphology of the Al deposit can be optimized by adjusting electrodeposition parameters. PB - University of Belgrade - Technical Faculty in Bor C3 - Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia T1 - Aluminium electrodeposition from chloroaluminate melts SP - 237 EP - 240 UR - https://hdl.handle.net/21.15107/rcub_cer_5870 ER -
@conference{ author = "Cvetković, Vesna S. and Vukićević, Nataša and Stevanović, Jasmina S. and Jovićević, Jovan N.", year = "2017", abstract = "Electrodeposited aluminium from a low temperature equimolar chloroaluminate melt onto a planar aluminium cathode was investigated. Experimental techniques used were linear sweep voltammetry, potential step and analytical techniques were SEM and EDS. Results show that a relatively adherent and compact aluminium deposit featuring high surface area can be successfully electrodeposited from melts at 200◦C. Electrodeposition done under potentiostatic control indicates that aluminium deposits are made up of extremely small particles of irregular shape and that a moderate increase in applied overpotential leads to decrease in crystallite down to nanoparticle size. Surface morphology of the Al deposit can be optimized by adjusting electrodeposition parameters.", publisher = "University of Belgrade - Technical Faculty in Bor", journal = "Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia", title = "Aluminium electrodeposition from chloroaluminate melts", pages = "237-240", url = "https://hdl.handle.net/21.15107/rcub_cer_5870" }
Cvetković, V. S., Vukićević, N., Stevanović, J. S.,& Jovićević, J. N.. (2017). Aluminium electrodeposition from chloroaluminate melts. in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia University of Belgrade - Technical Faculty in Bor., 237-240. https://hdl.handle.net/21.15107/rcub_cer_5870
Cvetković VS, Vukićević N, Stevanović JS, Jovićević JN. Aluminium electrodeposition from chloroaluminate melts. in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia. 2017;:237-240. https://hdl.handle.net/21.15107/rcub_cer_5870 .
Cvetković, Vesna S., Vukićević, Nataša, Stevanović, Jasmina S., Jovićević, Jovan N., "Aluminium electrodeposition from chloroaluminate melts" in Proceedings - The 49th International October Conference on Mining and Metallurgy, October 18-21, 2017, Bor Lake, Serbia (2017):237-240, https://hdl.handle.net/21.15107/rcub_cer_5870 .