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Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt

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2016
bitstream_24383.pdf (9.423Mb)
Authors
Vukićević, Nataša
Cvetković, Vesna S.
Stevanović, Jasmina S.
Jovićević, Jovan
Conference object (Published version)
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Abstract
Electrodeposition of Nb and Al onto platinum from equimolar AlC13+NaCl melt enriched with niobium ions was studied at 200 °C. Nb was introduced into the melt by anodic dissolution of Nb anode. Experimental techniques used for deposition and dissolution processes were cyclic voltammetry and potential step, and for analysis of the deposits obtained, scanning electron microscopy-SEM, X-ray diffraction-XRD and energy dispersive spectrometry-EDS. Niobium was deposited at overpotential individually and co-deposited with aluminium at aluminium overpotentials. It was found that Nb/Al, Nb/Pt, Al/Pt alloys were formed and Al and Nb deposited, depending on the potential applied.
Keywords:
niobium / aluminium / Al-Nb alloy / Nb-Pt alloy / chloroaluminate melts
Source:
Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia, 2016, 305-308
Publisher:
  • University of Belgrade - Technical Faculty in Bor

ISBN: 978-86-6305-047-1

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_5869
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/5869
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - CONF
AU  - Vukićević, Nataša
AU  - Cvetković, Vesna S.
AU  - Stevanović, Jasmina S.
AU  - Jovićević, Jovan
PY  - 2016
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5869
AB  - Electrodeposition of Nb and Al onto platinum from equimolar AlC13+NaCl melt enriched with niobium ions was studied at 200 °C. Nb was introduced into the melt by anodic dissolution of Nb anode. Experimental techniques used for deposition and dissolution processes were cyclic voltammetry and potential step, and for analysis of the deposits obtained, scanning electron microscopy-SEM, X-ray diffraction-XRD and energy dispersive spectrometry-EDS. Niobium was deposited at overpotential individually and co-deposited with aluminium at aluminium overpotentials. It was found that Nb/Al, Nb/Pt, Al/Pt alloys were formed and Al and Nb deposited, depending on the potential applied.
PB  - University of Belgrade - Technical Faculty in Bor
C3  - Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia
T1  - Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt
SP  - 305
EP  - 308
UR  - https://hdl.handle.net/21.15107/rcub_cer_5869
ER  - 
@conference{
author = "Vukićević, Nataša and Cvetković, Vesna S. and Stevanović, Jasmina S. and Jovićević, Jovan",
year = "2016",
abstract = "Electrodeposition of Nb and Al onto platinum from equimolar AlC13+NaCl melt enriched with niobium ions was studied at 200 °C. Nb was introduced into the melt by anodic dissolution of Nb anode. Experimental techniques used for deposition and dissolution processes were cyclic voltammetry and potential step, and for analysis of the deposits obtained, scanning electron microscopy-SEM, X-ray diffraction-XRD and energy dispersive spectrometry-EDS. Niobium was deposited at overpotential individually and co-deposited with aluminium at aluminium overpotentials. It was found that Nb/Al, Nb/Pt, Al/Pt alloys were formed and Al and Nb deposited, depending on the potential applied.",
publisher = "University of Belgrade - Technical Faculty in Bor",
journal = "Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia",
title = "Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt",
pages = "305-308",
url = "https://hdl.handle.net/21.15107/rcub_cer_5869"
}
Vukićević, N., Cvetković, V. S., Stevanović, J. S.,& Jovićević, J.. (2016). Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt. in Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia
University of Belgrade - Technical Faculty in Bor., 305-308.
https://hdl.handle.net/21.15107/rcub_cer_5869
Vukićević N, Cvetković VS, Stevanović JS, Jovićević J. Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt. in Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia. 2016;:305-308.
https://hdl.handle.net/21.15107/rcub_cer_5869 .
Vukićević, Nataša, Cvetković, Vesna S., Stevanović, Jasmina S., Jovićević, Jovan, "Alloy formation by al and nb electrodeposition from chloroaluminate low temperature melt" in Proceedings - The 48h International October Conference on Mining and Metallurgy, September 28 - October 01, 2016, Bor, Serbia (2016):305-308,
https://hdl.handle.net/21.15107/rcub_cer_5869 .

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