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dc.creatorTodorović, Tamara
dc.creatorRychlewska, Urszula
dc.creatorWarzajtis, B.
dc.creatorRadanović, Dušanka
dc.creatorFilipović, N.R.
dc.creatorPajić, I.A.
dc.creatorSladić, Dušan
dc.creatorAnđelković, Katarina
dc.date.accessioned2019-01-30T17:21:10Z
dc.date.available2019-01-30T17:21:10Z
dc.date.issued2009
dc.identifier.issn0277-5387
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/577
dc.description.abstractThe bimetallic [Ni2(H2L2)2](ClO4)4 (1), [Ni2(HL2)(H2L2)](ClO4)3 (2) and [Zn2(H2L2)2](BF4) 4 (3) complexes (H2L2 = N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedi hydrazide) were synthesized and characterized. The structure of complexes (1) and (2) was established by X-ray analysis. NMR spectroscopy was used for the characterization of complex (3). The complexes (1) and (2) were obtained from the same synthetic reaction and two crystal types of these complexes have been isolated during the fractional crystallization process. In complex (1) each Ni(II) ion is coordinated with two NNO donor atom sets from two H2L2 ligands forming an octahedral geometry. Similarly, in complex (2) the octahedral geometry of each Ni(II) ion is attained by coordination of two NNO donor atom sets, one from the neutral and the other from the monoanionic form of the ligand. The antimicrobial activity of the ligand and complexes is also presented.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142026/RS//
dc.rightsrestrictedAccess
dc.sourcePolyhedron
dc.subjectAntimicrobial activityen
dc.subjectMalonic acid dihydrazide derivativeen
dc.subjectNi(II) and Zn(II) complexesen
dc.subjectX-ray analysisen
dc.titleSynthesis, characterization and antimicrobial activity of Ni(II) and Zn(II) complexes with N′,N′2-bis[(1E)-1-(2-pyridyl)ethylidene]propanedi hydrazide. Crystal structures of two highly solvated bimetallic complexes of Ni(II)en
dc.typearticle
dc.rights.licenseARR
dcterms.abstractТодоровић, Тамара Р.; Пајић, И.A.; Филиповић, Н.Р.; Сладић, Д.М.; Рyцхлеwска, У.; Wарзајтис, Б.; Радановић, Душанка; Aнђелковић, Катарина;
dc.citation.volume28
dc.citation.issue12
dc.citation.spage2397
dc.citation.epage2402
dc.citation.other28(12): 2397-2402
dc.citation.rankM21
dc.identifier.doi10.1016/j.poly.2009.05.002
dc.identifier.rcubConv_4207
dc.identifier.scopus2-s2.0-67650333161
dc.identifier.wos000268994200014
dc.type.versionpublishedVersion


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