One-step conversion of ketones to conjugated acids using bromoform
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2009
Authors
Vitnik, Vesna
Ivanović, Milovan D.

Vitnik, Željko

Đorđević, Jelena B.

Žižak, Željko

Juranić, Zorica

Juranić, Ivan

Article (Published version)

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Phase-transfer-catalyzed (PTC) reactions of ketones with bromoform and aqueous lithium hydroxide in alcoholic solvent result in the formation of ,-unsaturated carboxylic acids. The reaction was performed at room temperature for 24h. The corresponding conjugated acids were obtained from cyclic or aromatic ketones, whereas bromo acids were obtained from 4-oxo-piperidine-1- carboxylic acid ethyl ester (13) and 4-oxo-piperidine-1-carboxylic acid tert-butyl ester (14).
Keywords:
,-unsaturated carboxylic acids / Bromoform / phase-transfer-catalyzed reactionSource:
Synthetic Communications, 2009, 39, 8, 1457-1471Funding / projects:
- Novi sintetički pristupi, molekulsko modelovanje i farmakološko ispitivanje heterocikličnih sistema sa azotom (RS-142074)
- Synthesis, characterization and activity of organic and coordination composition and their application in (bio) nanotechnology (RS-142010)
DOI: 10.1080/00397910802531955
ISSN: 0039-7911
WoS: 000264343400014
Scopus: 2-s2.0-67650257390
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IHTMTY - JOUR AU - Vitnik, Vesna AU - Ivanović, Milovan D. AU - Vitnik, Željko AU - Đorđević, Jelena B. AU - Žižak, Željko AU - Juranić, Zorica AU - Juranić, Ivan PY - 2009 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/576 AB - Phase-transfer-catalyzed (PTC) reactions of ketones with bromoform and aqueous lithium hydroxide in alcoholic solvent result in the formation of ,-unsaturated carboxylic acids. The reaction was performed at room temperature for 24h. The corresponding conjugated acids were obtained from cyclic or aromatic ketones, whereas bromo acids were obtained from 4-oxo-piperidine-1- carboxylic acid ethyl ester (13) and 4-oxo-piperidine-1-carboxylic acid tert-butyl ester (14). T2 - Synthetic Communications T1 - One-step conversion of ketones to conjugated acids using bromoform VL - 39 IS - 8 SP - 1457 EP - 1471 DO - 10.1080/00397910802531955 ER -
@article{ author = "Vitnik, Vesna and Ivanović, Milovan D. and Vitnik, Željko and Đorđević, Jelena B. and Žižak, Željko and Juranić, Zorica and Juranić, Ivan", year = "2009", abstract = "Phase-transfer-catalyzed (PTC) reactions of ketones with bromoform and aqueous lithium hydroxide in alcoholic solvent result in the formation of ,-unsaturated carboxylic acids. The reaction was performed at room temperature for 24h. The corresponding conjugated acids were obtained from cyclic or aromatic ketones, whereas bromo acids were obtained from 4-oxo-piperidine-1- carboxylic acid ethyl ester (13) and 4-oxo-piperidine-1-carboxylic acid tert-butyl ester (14).", journal = "Synthetic Communications", title = "One-step conversion of ketones to conjugated acids using bromoform", volume = "39", number = "8", pages = "1457-1471", doi = "10.1080/00397910802531955" }
Vitnik, V., Ivanović, M. D., Vitnik, Ž., Đorđević, J. B., Žižak, Ž., Juranić, Z.,& Juranić, I.. (2009). One-step conversion of ketones to conjugated acids using bromoform. in Synthetic Communications, 39(8), 1457-1471. https://doi.org/10.1080/00397910802531955
Vitnik V, Ivanović MD, Vitnik Ž, Đorđević JB, Žižak Ž, Juranić Z, Juranić I. One-step conversion of ketones to conjugated acids using bromoform. in Synthetic Communications. 2009;39(8):1457-1471. doi:10.1080/00397910802531955 .
Vitnik, Vesna, Ivanović, Milovan D., Vitnik, Željko, Đorđević, Jelena B., Žižak, Željko, Juranić, Zorica, Juranić, Ivan, "One-step conversion of ketones to conjugated acids using bromoform" in Synthetic Communications, 39, no. 8 (2009):1457-1471, https://doi.org/10.1080/00397910802531955 . .