Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites
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In this paper the series of poly(urethane-siloxane) copolymers and their clay nanocomposites were synthesized based on 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the part of the hard segments (HS) and α,ω-dihydroxy-poly(propyleneoxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) as the part of the soft segments (SS). Organomodified montmorillonite clay (Cloisite 30B®) was used as nanofiller in the amount of 1 wt.% within prepared nanocomposites. Mechanical properties and morphology of these polymers were investigated by dynamic mechanical thermal analysis (DMTA) and wide angle X-ray diffraction (XRD) measurements.
Keywords:
poly(urethane-siloxane) / copolymers / clay nanocomposites / Mechanical properties / morphologySource:
Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd, 2018, 24-24Publisher:
- Serbian Chemical Society
Funding / projects:
- Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
- Czech Science Foundation (GACR, Project No. 13-06700S)
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IHTMTY - CONF AU - Stefanović, Ivan AU - Špirkova, Milena AU - Pergal, Marija PY - 2018 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5754 AB - In this paper the series of poly(urethane-siloxane) copolymers and their clay nanocomposites were synthesized based on 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the part of the hard segments (HS) and α,ω-dihydroxy-poly(propyleneoxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) as the part of the soft segments (SS). Organomodified montmorillonite clay (Cloisite 30B®) was used as nanofiller in the amount of 1 wt.% within prepared nanocomposites. Mechanical properties and morphology of these polymers were investigated by dynamic mechanical thermal analysis (DMTA) and wide angle X-ray diffraction (XRD) measurements. PB - Serbian Chemical Society C3 - Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd T1 - Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites SP - 24 EP - 24 UR - https://hdl.handle.net/21.15107/rcub_cer_5754 ER -
@conference{ author = "Stefanović, Ivan and Špirkova, Milena and Pergal, Marija", year = "2018", abstract = "In this paper the series of poly(urethane-siloxane) copolymers and their clay nanocomposites were synthesized based on 4,4'-diphenylmethane diisocyanate and 1,4-butanediol as the part of the hard segments (HS) and α,ω-dihydroxy-poly(propyleneoxide)-b-poly(dimethylsiloxane)-b-poly(propylene oxide) as the part of the soft segments (SS). Organomodified montmorillonite clay (Cloisite 30B®) was used as nanofiller in the amount of 1 wt.% within prepared nanocomposites. Mechanical properties and morphology of these polymers were investigated by dynamic mechanical thermal analysis (DMTA) and wide angle X-ray diffraction (XRD) measurements.", publisher = "Serbian Chemical Society", journal = "Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd", title = "Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites", pages = "24-24", url = "https://hdl.handle.net/21.15107/rcub_cer_5754" }
Stefanović, I., Špirkova, M.,& Pergal, M.. (2018). Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites. in Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd Serbian Chemical Society., 24-24. https://hdl.handle.net/21.15107/rcub_cer_5754
Stefanović I, Špirkova M, Pergal M. Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites. in Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd. 2018;:24-24. https://hdl.handle.net/21.15107/rcub_cer_5754 .
Stefanović, Ivan, Špirkova, Milena, Pergal, Marija, "Mechanical properties and morphology of the poly(urethane-siloxane) copolymers and their clay nanocomposites" in Book of Abstracts - 6th Conference of Young Chemists of Serbia, 27. oktobar 2018, Beograd (2018):24-24, https://hdl.handle.net/21.15107/rcub_cer_5754 .