Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization
Samo za registrovane korisnike
2022
Autori
Rašljić Rafajilović, MilenaPergal, Marija
Spasenović, Marko
Vićentić, Teodora
Bajuk-Bogdanović, Danica
Vasiljević-Radović, Dana
Konferencijski prilog (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Laser induced graphenization (LIG) of polymer materials has recognized as the most promising method for fabrication of flexible electronic devices. Poly(dimethylsiloxane) (PDMS) is suitable elastomeric materials for flexible electronics devices fabrication due to outstanding mechanical and optical properties. Namely, the low carbon content and the lacking aromatic structures in PDMS material limit the graphenization process resulting in limited conduction properties. The aim of this study was the graphenization of PDMS and PDMS-based materials by CO2 laser radiation. We prepared pure PDMS elastomer, PDMS/ethylene glycol and PDMS/Triton composite materials by using 20 wt. % of ethylene glycol or Triton in PDMS matrix. Indeed, up to now the evidence of graphenization of these PDMS-based materials has never been observed. PDMS elastomer was prepared by hydrosilylation reaction, while composite materials by blending method. The prepared PDMS-based materials were characterized by Fourier-tr...ansform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and Raman spectroscopy. The obtained results showed that surfaces of pure PDMS elastomer and PDMS/ethylene glycol composite cannot be graphenized by direct laser writing. However, by adding Triton as aromatic and carbon sources into the PDMS matrix it is possible to improve the graphenization of PDMS based materials and this material is good candidate for fabrication of flexible electrodes.
Ključne reči:
Laser induced graphenization / electronic devices / Poly(dimethylsiloxane) / laser writingIzvor:
Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia, 2022, 87-87Izdavač:
- Belgrade : Serbian Ceramic Society
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200026 (Univerzitet u Beogradu, Institut za hemiju, tehnologiju i metalurgiju - IHTM) (RS-MESTD-inst-2020-200026)
Institucija/grupa
IHTMTY - CONF AU - Rašljić Rafajilović, Milena AU - Pergal, Marija AU - Spasenović, Marko AU - Vićentić, Teodora AU - Bajuk-Bogdanović, Danica AU - Vasiljević-Radović, Dana PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5750 AB - Laser induced graphenization (LIG) of polymer materials has recognized as the most promising method for fabrication of flexible electronic devices. Poly(dimethylsiloxane) (PDMS) is suitable elastomeric materials for flexible electronics devices fabrication due to outstanding mechanical and optical properties. Namely, the low carbon content and the lacking aromatic structures in PDMS material limit the graphenization process resulting in limited conduction properties. The aim of this study was the graphenization of PDMS and PDMS-based materials by CO2 laser radiation. We prepared pure PDMS elastomer, PDMS/ethylene glycol and PDMS/Triton composite materials by using 20 wt. % of ethylene glycol or Triton in PDMS matrix. Indeed, up to now the evidence of graphenization of these PDMS-based materials has never been observed. PDMS elastomer was prepared by hydrosilylation reaction, while composite materials by blending method. The prepared PDMS-based materials were characterized by Fourier-transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and Raman spectroscopy. The obtained results showed that surfaces of pure PDMS elastomer and PDMS/ethylene glycol composite cannot be graphenized by direct laser writing. However, by adding Triton as aromatic and carbon sources into the PDMS matrix it is possible to improve the graphenization of PDMS based materials and this material is good candidate for fabrication of flexible electrodes. PB - Belgrade : Serbian Ceramic Society C3 - Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia T1 - Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization SP - 87 EP - 87 UR - https://hdl.handle.net/21.15107/rcub_cer_5750 ER -
@conference{ author = "Rašljić Rafajilović, Milena and Pergal, Marija and Spasenović, Marko and Vićentić, Teodora and Bajuk-Bogdanović, Danica and Vasiljević-Radović, Dana", year = "2022", abstract = "Laser induced graphenization (LIG) of polymer materials has recognized as the most promising method for fabrication of flexible electronic devices. Poly(dimethylsiloxane) (PDMS) is suitable elastomeric materials for flexible electronics devices fabrication due to outstanding mechanical and optical properties. Namely, the low carbon content and the lacking aromatic structures in PDMS material limit the graphenization process resulting in limited conduction properties. The aim of this study was the graphenization of PDMS and PDMS-based materials by CO2 laser radiation. We prepared pure PDMS elastomer, PDMS/ethylene glycol and PDMS/Triton composite materials by using 20 wt. % of ethylene glycol or Triton in PDMS matrix. Indeed, up to now the evidence of graphenization of these PDMS-based materials has never been observed. PDMS elastomer was prepared by hydrosilylation reaction, while composite materials by blending method. The prepared PDMS-based materials were characterized by Fourier-transform infrared spectroscopy (FTIR), atomic force microscopy (AFM) and Raman spectroscopy. The obtained results showed that surfaces of pure PDMS elastomer and PDMS/ethylene glycol composite cannot be graphenized by direct laser writing. However, by adding Triton as aromatic and carbon sources into the PDMS matrix it is possible to improve the graphenization of PDMS based materials and this material is good candidate for fabrication of flexible electrodes.", publisher = "Belgrade : Serbian Ceramic Society", journal = "Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia", title = "Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization", pages = "87-87", url = "https://hdl.handle.net/21.15107/rcub_cer_5750" }
Rašljić Rafajilović, M., Pergal, M., Spasenović, M., Vićentić, T., Bajuk-Bogdanović, D.,& Vasiljević-Radović, D.. (2022). Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization. in Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia Belgrade : Serbian Ceramic Society., 87-87. https://hdl.handle.net/21.15107/rcub_cer_5750
Rašljić Rafajilović M, Pergal M, Spasenović M, Vićentić T, Bajuk-Bogdanović D, Vasiljević-Radović D. Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization. in Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia. 2022;:87-87. https://hdl.handle.net/21.15107/rcub_cer_5750 .
Rašljić Rafajilović, Milena, Pergal, Marija, Spasenović, Marko, Vićentić, Teodora, Bajuk-Bogdanović, Danica, Vasiljević-Radović, Dana, "Preparation of poly(dimethylsiloxane)-based materials for laser-induced graphenization" in Program and the book of abstracts - Serbian Ceramic Society Conference - Advanced Ceramics and Application X - New Frontiers in Multifunctional Material Science and Processing, 26-27. September 2022, Belgrade, Serbia (2022):87-87, https://hdl.handle.net/21.15107/rcub_cer_5750 .