Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s
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2004
Članak u časopisu (Objavljena verzija)
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Trans Tech Publications, Switzerland
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration
polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute
for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their
terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group
analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated.
Ključne reči:
Carboxypropyl-terminated Poly(siloxane)s / Dimethyldichlorosilane Hydrolysate / Equilibration PolymerizationIzvor:
Materials Science Forum, 2004, 453-454, 199-204Izdavač:
- Trans Tech Publications Ltd.
DOI: 10.4028/www.scientific.net/MSF.453-454.199
ISSN: 0255-5476
WoS: 000221535700035
Scopus: 2-s2.0-3142759499
Institucija/grupa
IHTMTY - JOUR AU - Antić, Mališa AU - Vučković, Marija V. AU - Antić, Vesna AU - Govedarica, Milutin PY - 2004 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5716 AB - A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated. PB - Trans Tech Publications Ltd. T2 - Materials Science Forum T1 - Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s VL - 453-454 SP - 199 EP - 204 DO - 10.4028/www.scientific.net/MSF.453-454.199 ER -
@article{ author = "Antić, Mališa and Vučković, Marija V. and Antić, Vesna and Govedarica, Milutin", year = "2004", abstract = "A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated.", publisher = "Trans Tech Publications Ltd.", journal = "Materials Science Forum", title = "Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s", volume = "453-454", pages = "199-204", doi = "10.4028/www.scientific.net/MSF.453-454.199" }
Antić, M., Vučković, M. V., Antić, V.,& Govedarica, M.. (2004). Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s. in Materials Science Forum Trans Tech Publications Ltd.., 453-454, 199-204. https://doi.org/10.4028/www.scientific.net/MSF.453-454.199
Antić M, Vučković MV, Antić V, Govedarica M. Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s. in Materials Science Forum. 2004;453-454:199-204. doi:10.4028/www.scientific.net/MSF.453-454.199 .
Antić, Mališa, Vučković, Marija V., Antić, Vesna, Govedarica, Milutin, "Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s" in Materials Science Forum, 453-454 (2004):199-204, https://doi.org/10.4028/www.scientific.net/MSF.453-454.199 . .