A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration
polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute
for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their
terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group
analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated.
TY - JOUR
AU - Antić, Mališa
AU - Vučković, Marija V.
AU - Antić, Vesna
AU - Govedarica, Milutin
PY - 2004
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5716
AB - A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration
polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute
for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their
terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group
analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated.
PB - Trans Tech Publications Ltd.
T2 - Materials Science Forum
T1 - Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s
VL - 453-454
SP - 199
EP - 204
DO - 10.4028/www.scientific.net/MSF.453-454.199
ER -
@article{
author = "Antić, Mališa and Vučković, Marija V. and Antić, Vesna and Govedarica, Milutin",
year = "2004",
abstract = "A number of carboxypropyl- terminated poly(siloxane)s were prepared using equilibration
polymerization reactions. Dimethyldichlorosilane hydrolysate, DDSH, was applied as a substitute
for the otherwise used cyclic siloxane monomers. As DDSH contains S-OH end-groups, it was of interest to analyze the obtained linear polymers with regard to the kind and amount of their
terminating units. In order to clarify this question, the IR and 1H NMR spectroscopy, end-group
analysis, vapor pressure osmometry and GPC detection methods were used. All the results showed that the polymers obtained from DDSH were carboxypropyl- terminated.",
publisher = "Trans Tech Publications Ltd.",
journal = "Materials Science Forum",
title = "Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s",
volume = "453-454",
pages = "199-204",
doi = "10.4028/www.scientific.net/MSF.453-454.199"
}
Antić, M., Vučković, M. V., Antić, V.,& Govedarica, M.. (2004). Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s. in Materials Science Forum
Trans Tech Publications Ltd.., 453-454, 199-204.
https://doi.org/10.4028/www.scientific.net/MSF.453-454.199
Antić M, Vučković MV, Antić V, Govedarica M. Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s. in Materials Science Forum. 2004;453-454:199-204.
doi:10.4028/www.scientific.net/MSF.453-454.199 .
Antić, Mališa, Vučković, Marija V., Antić, Vesna, Govedarica, Milutin, "Dimethyldichlorosilane Hydrolysate as a Substitute for Cyclic Monomers in the Preparation of Functional Poly(siloxane)s" in Materials Science Forum, 453-454 (2004):199-204,
https://doi.org/10.4028/www.scientific.net/MSF.453-454.199 . .
, 
