Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid
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2022
Authors
Šuljagić, MarijaStanković, Dalibor
Mirković, M.
Pavlović, V.
Petronijević, I.
Jeremić, Dejan
Anđelković, Ljubica
Article (Published version)
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Show full item recordAbstract
Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste electrode caus...ed a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer.
Keywords:
nickel ferrite / spinels / mechanochemical synthesis / acetylacetone complexes / sensorsSource:
Russian Journal of Inorganic Chemistry, 2022, 67, S1, S13-S21Publisher:
- Springer
Funding / projects:
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200116 (University of Belgrade, Faculty of Agriculture) (RS-200116)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-200017)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200162 (University of Belgrade, Faculty of Physics) (RS-200162)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200288 (Innovation Center of the Faculty of Chemistry) (RS-200288)
- Ministry of Science, Technological Development and Innovation of the Republic of Serbia, institutional funding - 200162 (University of Belgrade, Faculty of Physics) (RS-200162)
DOI: 10.1134/S003602362260201X
ISSN: 0036-0236; 1531-8613
Scopus: 2-s2.0-85145979242
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IHTMTY - JOUR AU - Šuljagić, Marija AU - Stanković, Dalibor AU - Mirković, M. AU - Pavlović, V. AU - Petronijević, I. AU - Jeremić, Dejan AU - Anđelković, Ljubica PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5618 AB - Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste electrode caused a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer. PB - Springer T2 - Russian Journal of Inorganic Chemistry T1 - Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid VL - 67 IS - S1 SP - S13 EP - S21 DO - 10.1134/S003602362260201X ER -
@article{ author = "Šuljagić, Marija and Stanković, Dalibor and Mirković, M. and Pavlović, V. and Petronijević, I. and Jeremić, Dejan and Anđelković, Ljubica", year = "2022", abstract = "Nickel ferrite nanoparticles were synthesized via thermal decomposition of β-diketonato complexes of nickel(II) and iron(III). The mechano-chemical activation of the complex precursors was used to ensure the increase in the reaction activity and consequently reduce thermal decomposition temperature. The prepared sample was thoroughly characterized by X-ray powder diffraction, FT-IR spectroscopy, scanning electron microscopy (SEM) coupled with electron dispersive spectroscopy (EDS), and transmission electron microscopy (TEM). X-ray powder diffraction and FT-IR confirmed the spinel phase of the investigated powder. SEM and TEM revealed the ultrafine nature of nanosized polygonal particles, with a pronounced agglomeration effect. The capacity for electrocatalytic applications was examined using cyclic voltammetry (CV) and electrical impedance spectroscopy (EIS). Electrocatalytic measurements pointed out that the addition of 5% of nickel ferrite as a modifier to carbon paste electrode caused a current increase and a decrease of the EIS semicircle. Further increase in the amount of the modifier decreased heterogeneity of the electrode surface and served as excellent sensor for the detection of gallic acid in the concentration range from 1 to 10 µM with the detection limit of 0.27 µM. This unambiguously indicated the significant improvement in electrode transfer rate and better characteristics of the diffusion layer.", publisher = "Springer", journal = "Russian Journal of Inorganic Chemistry", title = "Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid", volume = "67", number = "S1", pages = "S13-S21", doi = "10.1134/S003602362260201X" }
Šuljagić, M., Stanković, D., Mirković, M., Pavlović, V., Petronijević, I., Jeremić, D.,& Anđelković, L.. (2022). Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid. in Russian Journal of Inorganic Chemistry Springer., 67(S1), S13-S21. https://doi.org/10.1134/S003602362260201X
Šuljagić M, Stanković D, Mirković M, Pavlović V, Petronijević I, Jeremić D, Anđelković L. Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid. in Russian Journal of Inorganic Chemistry. 2022;67(S1):S13-S21. doi:10.1134/S003602362260201X .
Šuljagić, Marija, Stanković, Dalibor, Mirković, M., Pavlović, V., Petronijević, I., Jeremić, Dejan, Anđelković, Ljubica, "Novel Solid-State Approach to Nickel Ferrite Electrocatalyst for the Detection of Gallic Acid" in Russian Journal of Inorganic Chemistry, 67, no. S1 (2022):S13-S21, https://doi.org/10.1134/S003602362260201X . .