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TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications

Authorized Users Only
2022
Authors
Stojadinović, Stevan
Radić, Nenad
Tadić, Nenad
Vasilić, Rastko
Tsanev, Aleksander
Article (Published version)
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Abstract
TiO2 coatings modified by Bi2O3 particles were successfully formed by plasma electrolytic oxidation (PEO) process of titanium in supporting electrolyte (10 g/L Na3PO4·10H2O) with the addition of Bi2O3 particles. The morphology, crystal structure, chemical composition, and optical properties of formed PEO coatings were investigated by scanning electron microscopy, energy-dispersive spectroscopy, X-ray fluorescence, X-ray diffraction, X-ray photoelectron spectroscopy, UV–Vis diffuse reflectance spectroscopy, and photoluminescent techniques. The photodegradation of methyl orange under simulated sunlight condition was used to determine the potential of TiO2/Bi2O3 coatings in photocatalysis. The photocatalytic activity (PA) of TiO2/Bi2O3 coatings is higher than that of pure TiO2. PA of TiO2/Bi2O3 coatings is highly dependent on the amount of Bi2O3 particles in the supporting electrolyte and the highest PA was observed for TiO2/Bi2O3 coating formed in supporting electrolyte with the addition... of 1.2 g/L of Bi2O3 particles. Enhanced PA is related to the reduction of photo-generated electron/hole recombination rate as a result of TiO2 and Bi2O3 coupling.

Keywords:
oxidation / TiO2 / Bi2O3 / plasma electrolytic oxidation (PEO) / photocatalytic activity
Source:
Journal of Materials Science: Materials in Electronics, 2022, 33, 7, 4467-4481
Publisher:
  • Springer
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200162 (University of Belgrade, Faculty of Physics) (RS-200162)

DOI: 10.1007/s10854-021-07637-0

ISSN: 0957-4522; 1573-482X

WoS: 000749091400005

Scopus: 2-s2.0-85123867322
[ Google Scholar ]
1
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/5602
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Stojadinović, Stevan
AU  - Radić, Nenad
AU  - Tadić, Nenad
AU  - Vasilić, Rastko
AU  - Tsanev, Aleksander
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5602
AB  - TiO2 coatings modified by Bi2O3 particles were successfully formed by plasma electrolytic oxidation (PEO) process of titanium in supporting electrolyte (10 g/L Na3PO4·10H2O) with the addition of Bi2O3 particles. The morphology, crystal structure, chemical composition, and optical properties of formed PEO coatings were investigated by scanning electron microscopy, energy-dispersive spectroscopy, X-ray fluorescence, X-ray diffraction, X-ray photoelectron spectroscopy, UV–Vis diffuse reflectance spectroscopy, and photoluminescent techniques. The photodegradation of methyl orange under simulated sunlight condition was used to determine the potential of TiO2/Bi2O3 coatings in photocatalysis. The photocatalytic activity (PA) of TiO2/Bi2O3 coatings is higher than that of pure TiO2. PA of TiO2/Bi2O3 coatings is highly dependent on the amount of Bi2O3 particles in the supporting electrolyte and the highest PA was observed for TiO2/Bi2O3 coating formed in supporting electrolyte with the addition of 1.2 g/L of Bi2O3 particles. Enhanced PA is related to the reduction of photo-generated electron/hole recombination rate as a result of TiO2 and Bi2O3 coupling.
PB  - Springer
T2  - Journal of Materials Science: Materials in Electronics
T1  - TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications
VL  - 33
IS  - 7
SP  - 4467
EP  - 4481
DO  - 10.1007/s10854-021-07637-0
ER  - 
@article{
author = "Stojadinović, Stevan and Radić, Nenad and Tadić, Nenad and Vasilić, Rastko and Tsanev, Aleksander",
year = "2022",
abstract = "TiO2 coatings modified by Bi2O3 particles were successfully formed by plasma electrolytic oxidation (PEO) process of titanium in supporting electrolyte (10 g/L Na3PO4·10H2O) with the addition of Bi2O3 particles. The morphology, crystal structure, chemical composition, and optical properties of formed PEO coatings were investigated by scanning electron microscopy, energy-dispersive spectroscopy, X-ray fluorescence, X-ray diffraction, X-ray photoelectron spectroscopy, UV–Vis diffuse reflectance spectroscopy, and photoluminescent techniques. The photodegradation of methyl orange under simulated sunlight condition was used to determine the potential of TiO2/Bi2O3 coatings in photocatalysis. The photocatalytic activity (PA) of TiO2/Bi2O3 coatings is higher than that of pure TiO2. PA of TiO2/Bi2O3 coatings is highly dependent on the amount of Bi2O3 particles in the supporting electrolyte and the highest PA was observed for TiO2/Bi2O3 coating formed in supporting electrolyte with the addition of 1.2 g/L of Bi2O3 particles. Enhanced PA is related to the reduction of photo-generated electron/hole recombination rate as a result of TiO2 and Bi2O3 coupling.",
publisher = "Springer",
journal = "Journal of Materials Science: Materials in Electronics",
title = "TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications",
volume = "33",
number = "7",
pages = "4467-4481",
doi = "10.1007/s10854-021-07637-0"
}
Stojadinović, S., Radić, N., Tadić, N., Vasilić, R.,& Tsanev, A.. (2022). TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications. in Journal of Materials Science: Materials in Electronics
Springer., 33(7), 4467-4481.
https://doi.org/10.1007/s10854-021-07637-0
Stojadinović S, Radić N, Tadić N, Vasilić R, Tsanev A. TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications. in Journal of Materials Science: Materials in Electronics. 2022;33(7):4467-4481.
doi:10.1007/s10854-021-07637-0 .
Stojadinović, Stevan, Radić, Nenad, Tadić, Nenad, Vasilić, Rastko, Tsanev, Aleksander, "TiO2/Bi2O3 coatings formed by plasma electrolytic oxidation of titanium for photocatalytic applications" in Journal of Materials Science: Materials in Electronics, 33, no. 7 (2022):4467-4481,
https://doi.org/10.1007/s10854-021-07637-0 . .

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