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Regioselektivnost konjugovane adicijena monoalkil-1,4-benzohinone

dc.creatorBožić, Tatjana T.
dc.creatorSladić, Dušan
dc.creatorZlatović, Mario
dc.creatorNovaković, Irena
dc.creatorTrifunović, Snežana
dc.creatorGašić, Miroslav J.
dc.date.accessioned2019-01-30T17:10:03Z
dc.date.available2019-01-30T17:10:03Z
dc.date.issued2002
dc.identifier.issn0352-5139
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/55
dc.description.abstractThe regioselectivity of the reaction of conjugate addition of thiols amines, methanol and hydrogen chloride with the monoalkyl-1,4-benzoquinones avarone and 2-tert-butyl- 1,4-benzoquinone was investigated. It was shown that the regioselectivity of the reaction is influenced by the electrophilicity of position 5 in unprotonated 2-alkylquinones, the increased electrophilicity of position 6 in acidic medium, and by the acidity of the intermediate hydroquinones.en
dc.description.abstractProučavana je regioselektivnost konjugovane adicije tiola, amina, metanola i hlorovodonika na monoalkil-1,4-benzohinone avaron i 2-tert-butil-1,4-benzohinon. Pokazano je da na regioselektivnost reakcije utiču elektrofilnost položaja 5 neprotonovanih 2-alkil-hinona i povećana elektrofilnost položaja 6 u kiseloj sredini, kao i kiselost intermedijernih hidrohinona.sr
dc.publisherSerbian Chemical Society
dc.relationProject MESTD, br. 1586
dc.rightsopenAccess
dc.sourceJournal of the Serbian Chemical Society
dc.subjectquinoneen
dc.subjectavaroneen
dc.subjectconjugate additionen
dc.subjectregioselectivityen
dc.titleRegioselectivity of conjugate additions to monoalkyl-1,4-benzoquinonesen
dc.titleRegioselektivnost konjugovane adicijena monoalkil-1,4-benzohinonesr
dc.typearticle
dc.rights.licenseBY-NC-ND
dcterms.abstractНоваковић, Ирена; Златовић, Марио В.; Сладић, Душан М.; Божић, Татјана Т.; Гашић, Мирослав Ј.; Трифуновић, Снежана; Региоселективност коњуговане адицијена моноалкил-1,4-бензохиноне; Региоселективност коњуговане адицијена моноалкил-1,4-бензохиноне;
dc.citation.volume67
dc.citation.issue8-9
dc.citation.spage547
dc.citation.epage551
dc.citation.other67(8-9): 547-551
dc.citation.rankM23
dc.identifier.doi10.2298/JSC0209547B
dc.identifier.rcubConv_160
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs//bitstream/id/9183/53.pdf
dc.identifier.scopus2-s2.0-0036378018
dc.identifier.wos000178039500001
dc.type.versionpublishedVersion


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