Spatial distribution and source identification of heavy metals in European mountain beech forests soils
Samo za registrovane korisnike
2022
Autori
Štrbac, SnežanaRanđelović, Dragana
Gajica, Gordana
Hukić, Emira
Stojadinović, Sanja
Veselinović, Gorica
Orlić, Jovana
Tognetti, Roberto
Kašanin-Grubin, Milica
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The main objectives of this research were to (i) investigate the concentration; (ii) characterize the distribution; (iii) determine the sources apportionment; (iv) estimate environmental and health risks of heavy metals in soil from mountain beech forest. A total of 76 soil samples from 20 pure beech forest stands from Bosnia and Herzegovina (BA), Bulgaria (BG), Check Republic (CZ), Germany (DE), Italy (IT), Poland (PL), Romania (RO), Serbia (RS), Slovakia (SK), Slovenia (SL), and Spain (ES) were collected. The content of major elements was measured by X-ray fluorescence spectroscopy (XRF). The content of heavy metals was measured by inductively coupled plasma–optical emission spectrometry (ICP/OES). Heavy metals had a specific concentration range, which followed in soil samples from depth 0–40 cm the common order (low to high): Hg < Cd < As < Co < Pb < Ni < Cu < Cr < Zn, and from depth 40–80 cm: Hg < Cd < As < Pb < Co < Ni < Cu < Cr < Zn. The grouping of the examined parameters accord...ing to rock types, soil types, and localities indicated the separation of carbonate rocks from other substrates, luvisol, and rendzina from other soil types, and samples from BA, SL, and IT from other localities. According to sources apportionment As, Pb and Zn are of anthropogenic origin, Cd, Co, Cr, and Ni are of geogenic origin, while the middle position of Cu and Hg indicates a combined contribution of both sources. Elements Cd and Hg indicated severe to extremely severe enrichment with a mean value of 24.3 and 70.6, respectively. Based on the determined values Ni, Cr, As and Cd do not pose a health risk.
Ključne reči:
Principal component analysis / Geostatistical analysis / Source apportionment / Enrichment factor / Health riskIzvor:
Chemosphere, 2022, 309, 136662-Izdavač:
- Elsevier BV
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200026 (Univerzitet u Beogradu, Institut za hemiju, tehnologiju i metalurgiju - IHTM) (RS-MESTD-inst-2020-200026)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200023 (Institut za tehnologiju nuklearnih i drugih mineralnih sirovina - ITNMS, Beograd) (RS-MESTD-inst-2020-200023)
- COST action Climate-smart Forestry in Mountain Region CA15226 CLIMO
DOI: 10.1016/j.chemosphere.2022.136662
ISSN: 0045-6535
Scopus: 2-s2.0-85139275452
Institucija/grupa
IHTMTY - JOUR AU - Štrbac, Snežana AU - Ranđelović, Dragana AU - Gajica, Gordana AU - Hukić, Emira AU - Stojadinović, Sanja AU - Veselinović, Gorica AU - Orlić, Jovana AU - Tognetti, Roberto AU - Kašanin-Grubin, Milica PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5577 AB - The main objectives of this research were to (i) investigate the concentration; (ii) characterize the distribution; (iii) determine the sources apportionment; (iv) estimate environmental and health risks of heavy metals in soil from mountain beech forest. A total of 76 soil samples from 20 pure beech forest stands from Bosnia and Herzegovina (BA), Bulgaria (BG), Check Republic (CZ), Germany (DE), Italy (IT), Poland (PL), Romania (RO), Serbia (RS), Slovakia (SK), Slovenia (SL), and Spain (ES) were collected. The content of major elements was measured by X-ray fluorescence spectroscopy (XRF). The content of heavy metals was measured by inductively coupled plasma–optical emission spectrometry (ICP/OES). Heavy metals had a specific concentration range, which followed in soil samples from depth 0–40 cm the common order (low to high): Hg < Cd < As < Co < Pb < Ni < Cu < Cr < Zn, and from depth 40–80 cm: Hg < Cd < As < Pb < Co < Ni < Cu < Cr < Zn. The grouping of the examined parameters according to rock types, soil types, and localities indicated the separation of carbonate rocks from other substrates, luvisol, and rendzina from other soil types, and samples from BA, SL, and IT from other localities. According to sources apportionment As, Pb and Zn are of anthropogenic origin, Cd, Co, Cr, and Ni are of geogenic origin, while the middle position of Cu and Hg indicates a combined contribution of both sources. Elements Cd and Hg indicated severe to extremely severe enrichment with a mean value of 24.3 and 70.6, respectively. Based on the determined values Ni, Cr, As and Cd do not pose a health risk. PB - Elsevier BV T2 - Chemosphere T1 - Spatial distribution and source identification of heavy metals in European mountain beech forests soils VL - 309 SP - 136662 DO - 10.1016/j.chemosphere.2022.136662 ER -
@article{ author = "Štrbac, Snežana and Ranđelović, Dragana and Gajica, Gordana and Hukić, Emira and Stojadinović, Sanja and Veselinović, Gorica and Orlić, Jovana and Tognetti, Roberto and Kašanin-Grubin, Milica", year = "2022", abstract = "The main objectives of this research were to (i) investigate the concentration; (ii) characterize the distribution; (iii) determine the sources apportionment; (iv) estimate environmental and health risks of heavy metals in soil from mountain beech forest. A total of 76 soil samples from 20 pure beech forest stands from Bosnia and Herzegovina (BA), Bulgaria (BG), Check Republic (CZ), Germany (DE), Italy (IT), Poland (PL), Romania (RO), Serbia (RS), Slovakia (SK), Slovenia (SL), and Spain (ES) were collected. The content of major elements was measured by X-ray fluorescence spectroscopy (XRF). The content of heavy metals was measured by inductively coupled plasma–optical emission spectrometry (ICP/OES). Heavy metals had a specific concentration range, which followed in soil samples from depth 0–40 cm the common order (low to high): Hg < Cd < As < Co < Pb < Ni < Cu < Cr < Zn, and from depth 40–80 cm: Hg < Cd < As < Pb < Co < Ni < Cu < Cr < Zn. The grouping of the examined parameters according to rock types, soil types, and localities indicated the separation of carbonate rocks from other substrates, luvisol, and rendzina from other soil types, and samples from BA, SL, and IT from other localities. According to sources apportionment As, Pb and Zn are of anthropogenic origin, Cd, Co, Cr, and Ni are of geogenic origin, while the middle position of Cu and Hg indicates a combined contribution of both sources. Elements Cd and Hg indicated severe to extremely severe enrichment with a mean value of 24.3 and 70.6, respectively. Based on the determined values Ni, Cr, As and Cd do not pose a health risk.", publisher = "Elsevier BV", journal = "Chemosphere", title = "Spatial distribution and source identification of heavy metals in European mountain beech forests soils", volume = "309", pages = "136662", doi = "10.1016/j.chemosphere.2022.136662" }
Štrbac, S., Ranđelović, D., Gajica, G., Hukić, E., Stojadinović, S., Veselinović, G., Orlić, J., Tognetti, R.,& Kašanin-Grubin, M.. (2022). Spatial distribution and source identification of heavy metals in European mountain beech forests soils. in Chemosphere Elsevier BV., 309, 136662. https://doi.org/10.1016/j.chemosphere.2022.136662
Štrbac S, Ranđelović D, Gajica G, Hukić E, Stojadinović S, Veselinović G, Orlić J, Tognetti R, Kašanin-Grubin M. Spatial distribution and source identification of heavy metals in European mountain beech forests soils. in Chemosphere. 2022;309:136662. doi:10.1016/j.chemosphere.2022.136662 .
Štrbac, Snežana, Ranđelović, Dragana, Gajica, Gordana, Hukić, Emira, Stojadinović, Sanja, Veselinović, Gorica, Orlić, Jovana, Tognetti, Roberto, Kašanin-Grubin, Milica, "Spatial distribution and source identification of heavy metals in European mountain beech forests soils" in Chemosphere, 309 (2022):136662, https://doi.org/10.1016/j.chemosphere.2022.136662 . .