The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes

Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.

Keywords:

tungsten bronzes / electrochemical properties / impedance spectra / acid / proton / oxide / electrocatalysts / molybdenum / structural - characterization

Source:
Journal of Electrochemical Society, 2022, 169, 10, 106508-

Publisher:

The Electrochemical Society

Funding / projects:

Note:

This is the peer-reviewed version of the manuscript: Pagnacco M, Marković S, Potočnik J, Krstić V, Tančić P, Mojović M, Mojović Z. The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society. 2022;169(10):106508. doi: https://doi.org/10.1149/1945-7111/ac96ab
Published version: https://cer.ihtm.bg.ac.rs/handle/123456789/5387

Related info:

Version of
https://cer.ihtm.bg.ac.rs/handle/123456789/5387
Version of
https://doi.org/10.1149/1945-7111/ac96ab

DOI: 10.1149/1945-7111/ac96ab

ISSN: 0013-4651; 1945-7111

WoS: 000867405300001

TY  - JOUR
AU  - Pagnacco, Maja
AU  - Marković, Smilja
AU  - Potočnik, Jelena
AU  - Krstić, Vesna
AU  - Tančić, Pavle
AU  - Mojović, Miloš
AU  - Mojović, Zorica
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5553
AB  - Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.
PB  - The Electrochemical Society
T2  - Journal of Electrochemical Society
T1  - The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes
VL  - 169
IS  - 10
SP  - 106508
DO  - 10.1149/1945-7111/ac96ab
ER  -

@article{
author = "Pagnacco, Maja and Marković, Smilja and Potočnik, Jelena and Krstić, Vesna and Tančić, Pavle and Mojović, Miloš and Mojović, Zorica",
year = "2022",
abstract = "Phosphate tungsten bronze (WPB) and phosphate molybdenum bronze (MoPB) were synthesized and modified with rhenium. The existing phases were established by X-ray powder diffraction (XRPD), electron paramagnetic spectroscopy (EPR) and Field emission scanning electron microscopy (FESEM). The electroactivity of bronze samples, with and without rhenium for hydrogen evolution reaction (HER) was tested. The influence of carbon black presence in the catalytic ink on the electrochemical activity was investigated. Collected results provide insight into the effects of the constituents of an electrode on its electrochemical activity.",
publisher = "The Electrochemical Society",
journal = "Journal of Electrochemical Society",
title = "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes",
volume = "169",
number = "10",
pages = "106508",
doi = "10.1149/1945-7111/ac96ab"
}

Pagnacco, M., Marković, S., Potočnik, J., Krstić, V., Tančić, P., Mojović, M.,& Mojović, Z.. (2022). The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society
The Electrochemical Society., 169(10), 106508.
https://doi.org/10.1149/1945-7111/ac96ab

Pagnacco M, Marković S, Potočnik J, Krstić V, Tančić P, Mojović M, Mojović Z. The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes. in Journal of Electrochemical Society. 2022;169(10):106508.
doi:10.1149/1945-7111/ac96ab .

Pagnacco, Maja, Marković, Smilja, Potočnik, Jelena, Krstić, Vesna, Tančić, Pavle, Mojović, Miloš, Mojović, Zorica, "The Influence of Electrode Constituents on Hydrogen Evolution Reaction on Phosphate W- and Mo-Bronze-Based Electrodes" in Journal of Electrochemical Society, 169, no. 10 (2022):106508,
https://doi.org/10.1149/1945-7111/ac96ab . .