1,2-Dithioles
Abstract
The chemistry of 1,2-dithioles, 1,2-dithiolanes, 1,2-dithiolium salts, naphtho[1,8-cd]-1,2-dithiole, and 3,3aλ4,4-trithia-1-azapentalene is updated for the period 1995–2006. All X-ray determinations of structures containing these two nuclei are listed. New methods for the ring syntheses of 1,2-dithioles and 1,2-dithiolanes from various fragments are summarized and exemplified. The importance of through-space sulfur sulfur interactions is discussed. The relevance of lipoic acid to the synthesis of potential drugs, and self-assembled monolayers (SAMs) is described. Naturally occurring compounds containing the 1,2-dithiolane unit are exemplified. The biochemistry of lipoic acid is briefly discussed.
Keywords:
Dihydrolipoic acid (DHLA) / 1,2-Dithiolane / 1,2-Dithiole / 1,2-Dithiole-3-thiones / 1,2-Dithiolium salts / 1,2-Dithiol-3-ones / Leinamycin / Lipoic acid (LA) / Naphtho[1,8-cd]-1,2-dithiole / Thioxodesaurins / 3,3aλ4,4-Trithia-1-azapentalene / X-ray crystallographySource:
Comprehensive Heterocyclic Chemistry III, 2008, 4, 893-954Publisher:
- Elsevier
Funding / projects:
- The Ministry of Science, Technology and Development of the Republic of Serbia, grant no. 1709
Collections
Institution/Community
IHTMTY - CHAP AU - Marković, Rade AU - Rašović, Aleksandar PY - 2008 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5513 AB - The chemistry of 1,2-dithioles, 1,2-dithiolanes, 1,2-dithiolium salts, naphtho[1,8-cd]-1,2-dithiole, and 3,3aλ4,4-trithia-1-azapentalene is updated for the period 1995–2006. All X-ray determinations of structures containing these two nuclei are listed. New methods for the ring syntheses of 1,2-dithioles and 1,2-dithiolanes from various fragments are summarized and exemplified. The importance of through-space sulfur sulfur interactions is discussed. The relevance of lipoic acid to the synthesis of potential drugs, and self-assembled monolayers (SAMs) is described. Naturally occurring compounds containing the 1,2-dithiolane unit are exemplified. The biochemistry of lipoic acid is briefly discussed. PB - Elsevier T2 - Comprehensive Heterocyclic Chemistry III T1 - 1,2-Dithioles VL - 4 SP - 893 EP - 954 DO - 10.1016/B978-008044992-0.00411-9 ER -
@inbook{ author = "Marković, Rade and Rašović, Aleksandar", year = "2008", abstract = "The chemistry of 1,2-dithioles, 1,2-dithiolanes, 1,2-dithiolium salts, naphtho[1,8-cd]-1,2-dithiole, and 3,3aλ4,4-trithia-1-azapentalene is updated for the period 1995–2006. All X-ray determinations of structures containing these two nuclei are listed. New methods for the ring syntheses of 1,2-dithioles and 1,2-dithiolanes from various fragments are summarized and exemplified. The importance of through-space sulfur sulfur interactions is discussed. The relevance of lipoic acid to the synthesis of potential drugs, and self-assembled monolayers (SAMs) is described. Naturally occurring compounds containing the 1,2-dithiolane unit are exemplified. The biochemistry of lipoic acid is briefly discussed.", publisher = "Elsevier", journal = "Comprehensive Heterocyclic Chemistry III", booktitle = "1,2-Dithioles", volume = "4", pages = "893-954", doi = "10.1016/B978-008044992-0.00411-9" }
Marković, R.,& Rašović, A.. (2008). 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry III Elsevier., 4, 893-954. https://doi.org/10.1016/B978-008044992-0.00411-9
Marković R, Rašović A. 1,2-Dithioles. in Comprehensive Heterocyclic Chemistry III. 2008;4:893-954. doi:10.1016/B978-008044992-0.00411-9 .
Marković, Rade, Rašović, Aleksandar, "1,2-Dithioles" in Comprehensive Heterocyclic Chemistry III, 4 (2008):893-954, https://doi.org/10.1016/B978-008044992-0.00411-9 . .
Related items
Showing items related by title, author, creator and subject.
-
1,2-Dithioles
Rašović, Aleksandar (Elsevier, 2022) -
CCDC 607823: Experimental Crystal Structure Determination. Crystallographic data for "Regioselective synthesis of 1,3-thiazines by sequential 4-oxothiazolidine to 1,2-dithiole to 1,3-thiazine transformations: role of intramolecular non-bonded S/O interactions"
Rašović, Aleksandar; Steel, Peter J.; Kleinpeter, Erich; Marković, Rade (The Cambridge Crystallographic Data Centre (CCDC), 2007) -
Studies of the regioselective ring-opening closing mode of functionally different thiazolidine type enaminones: en route to the synthesis of trithiaazapentalene derivatives
Rašović, Aleksandar; Koch, Andreas; Kleinpeter, Erich; Marković, Rade (Oxford : Pergamon-Elsevier Science Ltd, 2013)