Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine
Само за регистроване кориснике
2022
Аутори
Stevanović, GordanaJović-Jovičić, Nataša
Krstić, Jugoslav
Milutinović Nikolić, Aleksandra
Banković, Predrag
Popović, Aleksandar
Ajduković, Marija
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Chitosan (Ch)-derived from biowaste along with smectite, an abundant clay mineral, were used in a low-cost and eco-friendly synthesis of a new type of catalyst. Nanocomposite catalysts constituted of Co supported on smectite with chitosan-derived carbon loading were obtained using an impregnation carbonization procedure and denoted as Co/cCh-S-T (T stands for applied carbonization temperature). The carbonization was performed in the temperature range from 400 °C to 700 °C in the flow of N2 providing inert atmosphere. The temperature of 500 °C was found to be the most suitable for catalyst synthesis regarding catalytic performance in a peroxymonosulfate activated degradation of tartrazine. The incorporation of carbonized chitosan structure within the interlamellar space of the smectite was confirmed using X-ray powder diffraction. The high-resolution transmission electron microscopy confirmed a layered structure of nanocomposites characteristic for smectite, as well as the presence of s...mall spherical cobalt containing nanoformations (confirmed by energy dispersive X-ray spectroscopy) well dispersed within structure. The existance of cobalt in the CoII and CoIII oxidation state was proven by X-ray photoelectron spectroscopy. The Co/cCh-S-500 catalyst was proven to be stable and efficient after 5 consecutive cycles. This work showed that nanocomposite Co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators exhibited a very promising performance in the degradation of water pollutants.
Кључне речи:
Biowaste / Cobalt / Peroxymonosulfate activation / Smectite / Tartrazine degradationИзвор:
Applied Clay Sciences, 2022, 230, 106718-Издавач:
- Elsevier
Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-200026)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200168 (Универзитет у Београду, Хемијски факултет) (RS-200168)
DOI: 10.1016/j.clay.2022.106718
ISSN: 0169-1317; 1872-9053
WoS: 000872391400008
Scopus: 2-s2.0-85139395176
Институција/група
IHTMTY - JOUR AU - Stevanović, Gordana AU - Jović-Jovičić, Nataša AU - Krstić, Jugoslav AU - Milutinović Nikolić, Aleksandra AU - Banković, Predrag AU - Popović, Aleksandar AU - Ajduković, Marija PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5437 AB - Chitosan (Ch)-derived from biowaste along with smectite, an abundant clay mineral, were used in a low-cost and eco-friendly synthesis of a new type of catalyst. Nanocomposite catalysts constituted of Co supported on smectite with chitosan-derived carbon loading were obtained using an impregnation carbonization procedure and denoted as Co/cCh-S-T (T stands for applied carbonization temperature). The carbonization was performed in the temperature range from 400 °C to 700 °C in the flow of N2 providing inert atmosphere. The temperature of 500 °C was found to be the most suitable for catalyst synthesis regarding catalytic performance in a peroxymonosulfate activated degradation of tartrazine. The incorporation of carbonized chitosan structure within the interlamellar space of the smectite was confirmed using X-ray powder diffraction. The high-resolution transmission electron microscopy confirmed a layered structure of nanocomposites characteristic for smectite, as well as the presence of small spherical cobalt containing nanoformations (confirmed by energy dispersive X-ray spectroscopy) well dispersed within structure. The existance of cobalt in the CoII and CoIII oxidation state was proven by X-ray photoelectron spectroscopy. The Co/cCh-S-500 catalyst was proven to be stable and efficient after 5 consecutive cycles. This work showed that nanocomposite Co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators exhibited a very promising performance in the degradation of water pollutants. PB - Elsevier T2 - Applied Clay Sciences T1 - Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine VL - 230 SP - 106718 DO - 10.1016/j.clay.2022.106718 ER -
@article{ author = "Stevanović, Gordana and Jović-Jovičić, Nataša and Krstić, Jugoslav and Milutinović Nikolić, Aleksandra and Banković, Predrag and Popović, Aleksandar and Ajduković, Marija", year = "2022", abstract = "Chitosan (Ch)-derived from biowaste along with smectite, an abundant clay mineral, were used in a low-cost and eco-friendly synthesis of a new type of catalyst. Nanocomposite catalysts constituted of Co supported on smectite with chitosan-derived carbon loading were obtained using an impregnation carbonization procedure and denoted as Co/cCh-S-T (T stands for applied carbonization temperature). The carbonization was performed in the temperature range from 400 °C to 700 °C in the flow of N2 providing inert atmosphere. The temperature of 500 °C was found to be the most suitable for catalyst synthesis regarding catalytic performance in a peroxymonosulfate activated degradation of tartrazine. The incorporation of carbonized chitosan structure within the interlamellar space of the smectite was confirmed using X-ray powder diffraction. The high-resolution transmission electron microscopy confirmed a layered structure of nanocomposites characteristic for smectite, as well as the presence of small spherical cobalt containing nanoformations (confirmed by energy dispersive X-ray spectroscopy) well dispersed within structure. The existance of cobalt in the CoII and CoIII oxidation state was proven by X-ray photoelectron spectroscopy. The Co/cCh-S-500 catalyst was proven to be stable and efficient after 5 consecutive cycles. This work showed that nanocomposite Co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators exhibited a very promising performance in the degradation of water pollutants.", publisher = "Elsevier", journal = "Applied Clay Sciences", title = "Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine", volume = "230", pages = "106718", doi = "10.1016/j.clay.2022.106718" }
Stevanović, G., Jović-Jovičić, N., Krstić, J., Milutinović Nikolić, A., Banković, P., Popović, A.,& Ajduković, M.. (2022). Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine. in Applied Clay Sciences Elsevier., 230, 106718. https://doi.org/10.1016/j.clay.2022.106718
Stevanović G, Jović-Jovičić N, Krstić J, Milutinović Nikolić A, Banković P, Popović A, Ajduković M. Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine. in Applied Clay Sciences. 2022;230:106718. doi:10.1016/j.clay.2022.106718 .
Stevanović, Gordana, Jović-Jovičić, Nataša, Krstić, Jugoslav, Milutinović Nikolić, Aleksandra, Banković, Predrag, Popović, Aleksandar, Ajduković, Marija, "Nanocomposite co-catalysts, based on smectite and biowaste-derived carbon, as peroxymonosulfate activators in degradation of tartrazine" in Applied Clay Sciences, 230 (2022):106718, https://doi.org/10.1016/j.clay.2022.106718 . .