The ligand ([HL]Cl) was synthetized by the reaction of 2-acetylpyridine and Girard's P reagent in molar ratio 1:1 in ethanol. In the reaction of ligand ([HL]Cl), nickel(II) tetrafluoroborate hexahydrate and sodium azide [Ni(HL)(N3)3] complex was obtained. The Ni(II) ion has a distorted octahedral coordination geometry. The tridentate ligand (HL) is coordinated to the nickel ion with an NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are supplemented by azido ligands. The ligand (HL) and the [Ni(HL)(N3)3] complex were characterized by elemental analysis, IR and UV/Vis spectroscopy and structure of the complex was defined by X-ray analysis.
Keywords:
coordination chemistry / X-ray crystallographic analysis / Ni(II) / synthesis / IR / UV/VIS / azido ligands / tridentate ligand
Source:
Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia, 2022, 75
TY - CONF
AU - Stevanović, Nevena
AU - Jevtović, Mima
AU - Čobeljić, Božidar
AU - Anđelković, Katarina
PY - 2022
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5384
AB - The ligand ([HL]Cl) was synthetized by the reaction of 2-acetylpyridine and Girard's P reagent in molar ratio 1:1 in ethanol. In the reaction of ligand ([HL]Cl), nickel(II) tetrafluoroborate hexahydrate and sodium azide [Ni(HL)(N3)3] complex was obtained. The Ni(II) ion has a distorted octahedral coordination geometry. The tridentate ligand (HL) is coordinated to the nickel ion with an NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are supplemented by azido ligands. The ligand (HL) and the [Ni(HL)(N3)3] complex were characterized by elemental analysis, IR and UV/Vis spectroscopy and structure of the complex was defined by X-ray analysis.
PB - Belgrade : Serbian Chemical Society
PB - Belgrade : Serbian Young Chemists’ Club
C3 - Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia
T1 - Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylpyridine and Girard's P reagent
IS - 75
UR - https://hdl.handle.net/21.15107/rcub_cer_5384
ER -
@conference{
author = "Stevanović, Nevena and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina",
year = "2022",
abstract = "The ligand ([HL]Cl) was synthetized by the reaction of 2-acetylpyridine and Girard's P reagent in molar ratio 1:1 in ethanol. In the reaction of ligand ([HL]Cl), nickel(II) tetrafluoroborate hexahydrate and sodium azide [Ni(HL)(N3)3] complex was obtained. The Ni(II) ion has a distorted octahedral coordination geometry. The tridentate ligand (HL) is coordinated to the nickel ion with an NNO set of donor atoms forming two five-membered chelate rings and the other three coordination sites are supplemented by azido ligands. The ligand (HL) and the [Ni(HL)(N3)3] complex were characterized by elemental analysis, IR and UV/Vis spectroscopy and structure of the complex was defined by X-ray analysis.",
publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists’ Club",
journal = "Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia",
title = "Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylpyridine and Girard's P reagent",
number = "75",
url = "https://hdl.handle.net/21.15107/rcub_cer_5384"
}
Stevanović, N., Jevtović, M., Čobeljić, B.,& Anđelković, K.. (2022). Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylpyridine and Girard's P reagent. in Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia
Belgrade : Serbian Chemical Society.(75).
https://hdl.handle.net/21.15107/rcub_cer_5384
Stevanović N, Jevtović M, Čobeljić B, Anđelković K. Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylpyridine and Girard's P reagent. in Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia. 2022;(75).
https://hdl.handle.net/21.15107/rcub_cer_5384 .
Stevanović, Nevena, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylpyridine and Girard's P reagent" in Book of Abstracts - 8th Conference of Young Chemists of Serbia, 29th October, 2022, Belgrade, Serbia, no. 75 (2022),
https://hdl.handle.net/21.15107/rcub_cer_5384 .
