Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide
Конференцијски прилог (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The ligand (HL) was synthetized by the reaction of 2-acetylthiazole and
thiosemicarbazide in molar ratio 1:1 in water. In the reaction of ligand (HL) and
nickel(II) tetrafluoroborate hexahydrate [Ni(HL)2](BF4)2 complex was obtained. The
Ni(II) ion has octahedral coordination geometry. The tridentate ligand (HL) is
coordinated to the nickel ion with a NNS set of donor atoms forming two five-
-membered chelate rings. The ligand (HL) and the [Ni(HL)2](BF4)2 complex were
characterized by elemental analysis, IR and UV/Vis spectroscopy and the structure of
the complex was defined by X-ray analysis.
Кључне речи:
coordination chemistry / X-ray crystallographic analysis / Ni(II) / synthesis / IR / UV/VIS / 2-acetylthiazole / thiosemicarbazide / tridentate ligandИзвор:
Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022, 2022, 72Издавач:
- Belgrade : Serbian Chemical Society
- Belgrade : Serbian Young Chemists’ Club
Финансирање / пројекти:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-ScienceFundRS-Ideje-7750288)
Напомена:
Повезане информације:
- Повезани садржај
https://cer.ihtm.bg.ac.rs/handle/123456789/5382
Институција/група
IHTMTY - CONF AU - Savić, Milica AU - Jevtović, Mima AU - Čobeljić, Božidar AU - Anđelković, Katarina PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5381 AB - The ligand (HL) was synthetized by the reaction of 2-acetylthiazole and thiosemicarbazide in molar ratio 1:1 in water. In the reaction of ligand (HL) and nickel(II) tetrafluoroborate hexahydrate [Ni(HL)2](BF4)2 complex was obtained. The Ni(II) ion has octahedral coordination geometry. The tridentate ligand (HL) is coordinated to the nickel ion with a NNS set of donor atoms forming two five- -membered chelate rings. The ligand (HL) and the [Ni(HL)2](BF4)2 complex were characterized by elemental analysis, IR and UV/Vis spectroscopy and the structure of the complex was defined by X-ray analysis. PB - Belgrade : Serbian Chemical Society PB - Belgrade : Serbian Young Chemists’ Club C3 - Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022 T1 - Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide IS - 72 UR - https://hdl.handle.net/21.15107/rcub_cer_5381 ER -
@conference{ author = "Savić, Milica and Jevtović, Mima and Čobeljić, Božidar and Anđelković, Katarina", year = "2022", abstract = "The ligand (HL) was synthetized by the reaction of 2-acetylthiazole and thiosemicarbazide in molar ratio 1:1 in water. In the reaction of ligand (HL) and nickel(II) tetrafluoroborate hexahydrate [Ni(HL)2](BF4)2 complex was obtained. The Ni(II) ion has octahedral coordination geometry. The tridentate ligand (HL) is coordinated to the nickel ion with a NNS set of donor atoms forming two five- -membered chelate rings. The ligand (HL) and the [Ni(HL)2](BF4)2 complex were characterized by elemental analysis, IR and UV/Vis spectroscopy and the structure of the complex was defined by X-ray analysis.", publisher = "Belgrade : Serbian Chemical Society, Belgrade : Serbian Young Chemists’ Club", journal = "Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022", title = "Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide", number = "72", url = "https://hdl.handle.net/21.15107/rcub_cer_5381" }
Savić, M., Jevtović, M., Čobeljić, B.,& Anđelković, K.. (2022). Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide. in Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022 Belgrade : Serbian Chemical Society.(72). https://hdl.handle.net/21.15107/rcub_cer_5381
Savić M, Jevtović M, Čobeljić B, Anđelković K. Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide. in Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022. 2022;(72). https://hdl.handle.net/21.15107/rcub_cer_5381 .
Savić, Milica, Jevtović, Mima, Čobeljić, Božidar, Anđelković, Katarina, "Synthesis and characterization of octahedral Ni(II) complex with condensation product of 2-acetylthiazole and thiosemicarbazide" in Book of Abstracts - 8th Conference of Young Chemists of Serbia, Belgrade, Serbia, 29th October, 2022, no. 72 (2022), https://hdl.handle.net/21.15107/rcub_cer_5381 .