Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst
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2009
Authors
Tripković, AmalijaPopović, Ksenija

Lović, Jelena

Jovanović, Vladislava M.

Stevanović, Sanja

Tripković, Dušan

Kowal, Andrzej

Article (Published version)

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Oxidation of ethanol was studied at Sn-ad modified and unmodified Pt3Sn/C and Pt/C catalysts. Pt3Sn/C and Pt/C catalysts were characterized by XRD. Potentiodynamic and chronoamperometric measurements were used to establish catalytic activity and stability. High activity achieved at Sn-ad modified Pt3Sn/C catalyst has not been observed at any bimetallic catalyst so far. Promotional effect of Sn-ad on the ethanol oxidation was related to the enhancement of CO oxidation rate in bifunctional mechanism. It was shown that electrodeposited Sn exhibited different effect on the catalytic activity compared to Sn in alloy.
Keywords:
Ethanol oxidation / Sn adlayer / Pt3Sn/C / Pt/C / XRDSource:
Electrochemistry Communications, 2009, 11, 5, 1030-1033Publisher:
- Elsevier Science Inc, New York
Funding / projects:
DOI: 10.1016/j.elecom.2009.03.004
ISSN: 1388-2481
WoS: 000266538200025
Scopus: 2-s2.0-67349151087
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IHTMTY - JOUR AU - Tripković, Amalija AU - Popović, Ksenija AU - Lović, Jelena AU - Jovanović, Vladislava M. AU - Stevanović, Sanja AU - Tripković, Dušan AU - Kowal, Andrzej PY - 2009 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/532 AB - Oxidation of ethanol was studied at Sn-ad modified and unmodified Pt3Sn/C and Pt/C catalysts. Pt3Sn/C and Pt/C catalysts were characterized by XRD. Potentiodynamic and chronoamperometric measurements were used to establish catalytic activity and stability. High activity achieved at Sn-ad modified Pt3Sn/C catalyst has not been observed at any bimetallic catalyst so far. Promotional effect of Sn-ad on the ethanol oxidation was related to the enhancement of CO oxidation rate in bifunctional mechanism. It was shown that electrodeposited Sn exhibited different effect on the catalytic activity compared to Sn in alloy. PB - Elsevier Science Inc, New York T2 - Electrochemistry Communications T1 - Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst VL - 11 IS - 5 SP - 1030 EP - 1033 DO - 10.1016/j.elecom.2009.03.004 ER -
@article{ author = "Tripković, Amalija and Popović, Ksenija and Lović, Jelena and Jovanović, Vladislava M. and Stevanović, Sanja and Tripković, Dušan and Kowal, Andrzej", year = "2009", abstract = "Oxidation of ethanol was studied at Sn-ad modified and unmodified Pt3Sn/C and Pt/C catalysts. Pt3Sn/C and Pt/C catalysts were characterized by XRD. Potentiodynamic and chronoamperometric measurements were used to establish catalytic activity and stability. High activity achieved at Sn-ad modified Pt3Sn/C catalyst has not been observed at any bimetallic catalyst so far. Promotional effect of Sn-ad on the ethanol oxidation was related to the enhancement of CO oxidation rate in bifunctional mechanism. It was shown that electrodeposited Sn exhibited different effect on the catalytic activity compared to Sn in alloy.", publisher = "Elsevier Science Inc, New York", journal = "Electrochemistry Communications", title = "Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst", volume = "11", number = "5", pages = "1030-1033", doi = "10.1016/j.elecom.2009.03.004" }
Tripković, A., Popović, K., Lović, J., Jovanović, V. M., Stevanović, S., Tripković, D.,& Kowal, A.. (2009). Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst. in Electrochemistry Communications Elsevier Science Inc, New York., 11(5), 1030-1033. https://doi.org/10.1016/j.elecom.2009.03.004
Tripković A, Popović K, Lović J, Jovanović VM, Stevanović S, Tripković D, Kowal A. Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst. in Electrochemistry Communications. 2009;11(5):1030-1033. doi:10.1016/j.elecom.2009.03.004 .
Tripković, Amalija, Popović, Ksenija, Lović, Jelena, Jovanović, Vladislava M., Stevanović, Sanja, Tripković, Dušan, Kowal, Andrzej, "Promotional effect of Sn-ad on the ethanol oxidation at Pt3Sn/C catalyst" in Electrochemistry Communications, 11, no. 5 (2009):1030-1033, https://doi.org/10.1016/j.elecom.2009.03.004 . .