The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of th...e adsorption process, as well as regeneration of the polymeric sorbents were discussed.
Keywords:
adsorption mechanisms / desorption / EGDMA / heavy metal(loid)s / isotherms / kinetics / magnetic sorbents / reusability
TY - JOUR
AU - Nastasović, Aleksandra
AU - Marković, Bojana
AU - Suručić, Ljiljana
AU - Onjia, Antonije
PY - 2022
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5245
AB - The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.
PB - MDPI
T2 - Metals
T1 - Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions
VL - 12
IS - 5
SP - 814
DO - 10.3390/met12050814
ER -
@article{
author = "Nastasović, Aleksandra and Marković, Bojana and Suručić, Ljiljana and Onjia, Antonije",
year = "2022",
abstract = "The industrialization and urbanization expansion have increased the demand for precious and rare earth elements (REEs). In addition, environmental concerns regarding the toxic effects of heavy metals on living organisms imposed an urgent need for efficient methods for their removal from wastewaters and aqueous solutions. The most efficient technique for metal ions removal from wastewaters is adsorption due to its reversibility and high efficiency. Numerous adsorbents were mentioned as possible metal ions adsorbents in the literature. Chelating polymer ligands (CPLs) with adaptable surface chemistry, high affinity towards targeted metal ions, high capacity, fast kinetics, chemically stable, and reusable are especially attractive. This review is focused on methacrylatebased magnetic and non-magnetic porous sorbents. Special attention was devoted to amino-modified glycidyl methacrylate (GMA) copolymers. Main adsorption parameters, kinetic models, adsorption isotherms, thermodynamics of the adsorption process, as well as regeneration of the polymeric sorbents were discussed.",
publisher = "MDPI",
journal = "Metals",
title = "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions",
volume = "12",
number = "5",
pages = "814",
doi = "10.3390/met12050814"
}
Nastasović, A., Marković, B., Suručić, L.,& Onjia, A.. (2022). Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals
MDPI., 12(5), 814.
https://doi.org/10.3390/met12050814
Nastasović A, Marković B, Suručić L, Onjia A. Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions. in Metals. 2022;12(5):814.
doi:10.3390/met12050814 .
Nastasović, Aleksandra, Marković, Bojana, Suručić, Ljiljana, Onjia, Antonije, "Methacrylate-Based Polymeric Sorbents for Recovery of Metals from Aqueous Solutions" in Metals, 12, no. 5 (2022):814,
https://doi.org/10.3390/met12050814 . .
