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Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and DFT calculation

Hidrazonski kompleksi Cu(II), Mn(II) i Zn(II) sa kvaternernim amonijum fragmentom: sinteza, karakterizacija i DFT proračuni

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2022
SHD58_Book_of_abstracts_3.pdf (594.9Kb)
Authors
Stevanović, Nevena
Zlatar, Matija
Jevtović, Mima
Gruden, Maja
Šumar, Maja
Anđelković, Katarina
Čobeljić, Božidar
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Abstract
The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations.
U reakciji liganda HLCl sa solima metala Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O i NaN3 u metanolu, dobijeni su mononuklearni kompleksi koordinacionog broja pet: [CuL(N3)(CH3OH)]BF4 (1) i [ZnL(N3)2] (2) i dinuklearni kompleks [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3). Kompleksi 1, 2 i 3 okarakterisani su elementalnom analizom, IC spektroskopijom, rendgenskom stukturnom analizom i DFT proračunima.
Keywords:
coordination chemistry / X-ray crystallographic analysis / DFT / Schiff base ligands / Cu(II) / Mn(II) / Zn(II)
Source:
Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine, 2022, 127-
Publisher:
  • Belgrade : Serbian Chemical Society
Funding / projects:
  • TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-7750288)
Note:
  • Poster: https://cer.ihtm.bg.ac.rs/handle/123456789/5085
Related info:
  • Referenced by
    https://cer.ihtm.bg.ac.rs/handle/123456789/5085

ISBN: 978-86-7132-079-5

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_5081
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/5081
Collections
  • TMMagCat
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - CONF
AU  - Stevanović, Nevena
AU  - Zlatar, Matija
AU  - Jevtović, Mima
AU  - Gruden, Maja
AU  - Šumar, Maja
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5081
AB  - The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations.
AB  - U reakciji liganda HLCl sa solima metala Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O i NaN3 u metanolu, dobijeni su mononuklearni kompleksi koordinacionog broja pet: [CuL(N3)(CH3OH)]BF4 (1) i [ZnL(N3)2] (2) i dinuklearni kompleks [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3). Kompleksi 1, 2 i 3 okarakterisani su elementalnom analizom, IC spektroskopijom, rendgenskom stukturnom analizom i DFT proračunima.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
T1  - Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation
T1  - Hidrazonski kompleksi Cu(II), Mn(II) i Zn(II) sa kvaternernim  amonijum fragmentom: sinteza, karakterizacija i DFT proračuni
SP  - 127
UR  - https://hdl.handle.net/21.15107/rcub_cer_5081
ER  - 
@conference{
author = "Stevanović, Nevena and Zlatar, Matija and Jevtović, Mima and Gruden, Maja and Šumar, Maja and Anđelković, Katarina and Čobeljić, Božidar",
year = "2022",
abstract = "The HLCl ligand with metal salts Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O and NaN3, in methanol form mononuclear penta-coordinated complexes [CuL(N3)(CH3OH)]BF4 (1) and [ZnL(N3)2] (2) and binuclear [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3) complex. Complexes 1, 2 and 3 were characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, and DFT calculations., U reakciji liganda HLCl sa solima metala Cu(BF4)2‧6H2O / MnCl2‧4H2O / Zn(BF4)2‧6H2O i NaN3 u metanolu, dobijeni su mononuklearni kompleksi koordinacionog broja pet: [CuL(N3)(CH3OH)]BF4 (1) i [ZnL(N3)2] (2) i dinuklearni kompleks [Mn2L2(µ-1,1-N3)2(N3)2]⋅2CH3OH (3). Kompleksi 1, 2 i 3 okarakterisani su elementalnom analizom, IC spektroskopijom, rendgenskom stukturnom analizom i DFT proračunima.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine",
title = "Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation, Hidrazonski kompleksi Cu(II), Mn(II) i Zn(II) sa kvaternernim  amonijum fragmentom: sinteza, karakterizacija i DFT proračuni",
pages = "127",
url = "https://hdl.handle.net/21.15107/rcub_cer_5081"
}
Stevanović, N., Zlatar, M., Jevtović, M., Gruden, M., Šumar, M., Anđelković, K.,& Čobeljić, B.. (2022). Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
Belgrade : Serbian Chemical Society., 127.
https://hdl.handle.net/21.15107/rcub_cer_5081
Stevanović N, Zlatar M, Jevtović M, Gruden M, Šumar M, Anđelković K, Čobeljić B. Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine. 2022;:127.
https://hdl.handle.net/21.15107/rcub_cer_5081 .
Stevanović, Nevena, Zlatar, Matija, Jevtović, Mima, Gruden, Maja, Šumar, Maja, Anđelković, Katarina, Čobeljić, Božidar, "Cu(II), Mn(II) and Zn(II) complexes of hydrazones with quaternary ammonium moiety: Synthesis, characterization and  DFT calculation" in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine (2022):127,
https://hdl.handle.net/21.15107/rcub_cer_5081 .

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