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Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole

Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola

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2022
SHD58_Book_of_abstracts_2.pdf (548.1Kb)
Authors
Savić, Milica
Stevanović, Nevena
Jevtović, Mima
Gruden, Maja
Anđelković, Katarina
Čobeljić, Božidar
Zlatar, Matija
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Abstract
The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur.
Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 : 4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe.
Keywords:
coordination chemistry / X-ray crystallographic analysis / Fe(III) / Mn(II) / Schiff base ligands / synthesis
Source:
Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine, 2022, 126-
Publisher:
  • Belgrade : Serbian Chemical Society
Funding / projects:
  • TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-7750288)
Note:
  • Poster: https://cer.ihtm.bg.ac.rs/handle/123456789/5083
Related info:
  • Referenced by
    https://cer.ihtm.bg.ac.rs/handle/123456789/5083

ISBN: 978-86-7132-079-5

[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_cer_5080
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/5080
Collections
  • TMMagCat
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - CONF
AU  - Savić, Milica
AU  - Stevanović, Nevena
AU  - Jevtović, Mima
AU  - Gruden, Maja
AU  - Anđelković, Katarina
AU  - Čobeljić, Božidar
AU  - Zlatar, Matija
PY  - 2022
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/5080
AB  - The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar 
ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in 
the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by 
elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand 
molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur.
AB  - Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 : 
4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks 
Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe.
PB  - Belgrade : Serbian Chemical Society
C3  - Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
T1  - Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole
T1  - Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola
SP  - 126
UR  - https://hdl.handle.net/21.15107/rcub_cer_5080
ER  - 
@conference{
author = "Savić, Milica and Stevanović, Nevena and Jevtović, Mima and Gruden, Maja and Anđelković, Katarina and Čobeljić, Božidar and Zlatar, Matija",
year = "2022",
abstract = "The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar 
ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in 
the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by 
elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand 
molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur., Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 : 
4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks 
Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine",
title = "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole, Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola",
pages = "126",
url = "https://hdl.handle.net/21.15107/rcub_cer_5080"
}
Savić, M., Stevanović, N., Jevtović, M., Gruden, M., Anđelković, K., Čobeljić, B.,& Zlatar, M.. (2022). Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
Belgrade : Serbian Chemical Society., 126.
https://hdl.handle.net/21.15107/rcub_cer_5080
Savić M, Stevanović N, Jevtović M, Gruden M, Anđelković K, Čobeljić B, Zlatar M. Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine. 2022;:126.
https://hdl.handle.net/21.15107/rcub_cer_5080 .
Savić, Milica, Stevanović, Nevena, Jevtović, Mima, Gruden, Maja, Anđelković, Katarina, Čobeljić, Božidar, Zlatar, Matija, "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole" in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine (2022):126,
https://hdl.handle.net/21.15107/rcub_cer_5080 .

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