Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole
Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola
Authors
Savić, Milica
Stevanović, Nevena

Jevtović, Mima

Gruden, Maja

Anđelković, Katarina

Čobeljić, Božidar

Zlatar, Matija

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The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar
ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in
the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by
elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand
molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur.
Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 :
4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks
Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe.
Keywords:
coordination chemistry / X-ray crystallographic analysis / Fe(III) / Mn(II) / Schiff base ligands / synthesisSource:
Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine, 2022, 126-Publisher:
- Belgrade : Serbian Chemical Society
Funding / projects:
- TMMagCat - Tailoring Molecular Magnets and Catalysts Based on Transition Metal Complexes (RS-7750288)
Note:
Related info:
- Referenced by
https://cer.ihtm.bg.ac.rs/handle/123456789/5083
Institution/Community
IHTMTY - CONF AU - Savić, Milica AU - Stevanović, Nevena AU - Jevtović, Mima AU - Gruden, Maja AU - Anđelković, Katarina AU - Čobeljić, Božidar AU - Zlatar, Matija PY - 2022 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5080 AB - The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur. AB - Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 : 4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe. PB - Belgrade : Serbian Chemical Society C3 - Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine T1 - Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole T1 - Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola SP - 126 UR - https://hdl.handle.net/21.15107/rcub_cer_5080 ER -
@conference{ author = "Savić, Milica and Stevanović, Nevena and Jevtović, Mima and Gruden, Maja and Anđelković, Katarina and Čobeljić, Božidar and Zlatar, Matija", year = "2022", abstract = "The HL ligand was synthesized in the reaction of thiosemicarbazide and 2-acetylthiazole in molar ratio 1:1 in water, with 3 drops of 2M HCl. Complex [Fe(L)2]BF4·H2O (1) was synthesized in the reaction of ligand and Fe(BF4)6·6H2O in MeOH, after complete dissolution of Fe(BF4)2·6H2O in the reaction mixture, NaN3 was added. In the reaction of ligand (HL), MnCl2·4H2O and NaN3, in molar rotio 1 : 1 : 4, Mn(II) complex (2) was obtained. Complexes 1 and 2 were characterized by elemental analysis, IR and UV/Vis spectroscopy and X-ray crystallographic analysis. Both complexes 1 and 2 with HL ligand are bis octahedral complexes in which two deprotonated ligand molecules coordinate in a mer arrangement through two NNS sets of donor atoms, through thiazole and imine nitrogens and thioenolate sulfur., Ligand (HL) sintetisan je u reakciji tiosemikarbazida i 2-acetiltiazola u molarnom odnosu 1 : 1 u vodi, u kiseloj sredini. Kompleks [Fe(L)2]BF4·H2O (1) dobijen je u reakciji liganda i Fe(BF4)2·6H2O u metanolu i nakon potpunog rastvaranja Fe(II) soli dodat je NaN3 u višku (1 : 1 : 4). U reakciji liganda (HL), MnCl2·4H2O i NaN3 u molarnom odnosu 1 : 1 : 4, dobijen je kompleks Mn(II), [Mn(L)2] (2). Kompleksi 1 i 2 okarakterisani su elementalnom analizom, IC spektroskopijom, UV/Vis spektroskopijom i rendgenskom strukturnom analizom. Kod oba kompleksa 1 i 2 dolazi do forimiranja bis oktaedarske geometrije tako što se za centralni metalni jon koordinuju dva deprotonovana liganda preko dva NNS donorska seta atoma u mer okruženju. Do koordinacije liganda za centralni metalni jon, kako Fe(III), tako i Mn(II), dolazi preko dva azota, od kojih jedan potiče iz tiazola, a drugi iz iminske grupe, kao i preko sumpora iz tioenolatne grupe.", publisher = "Belgrade : Serbian Chemical Society", journal = "Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine", title = "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole, Sinteza i karakterizacija kompleksa Fe(III) i Mn(II) sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola", pages = "126", url = "https://hdl.handle.net/21.15107/rcub_cer_5080" }
Savić, M., Stevanović, N., Jevtović, M., Gruden, M., Anđelković, K., Čobeljić, B.,& Zlatar, M.. (2022). Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine Belgrade : Serbian Chemical Society., 126. https://hdl.handle.net/21.15107/rcub_cer_5080
Savić M, Stevanović N, Jevtović M, Gruden M, Anđelković K, Čobeljić B, Zlatar M. Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine. 2022;:126. https://hdl.handle.net/21.15107/rcub_cer_5080 .
Savić, Milica, Stevanović, Nevena, Jevtović, Mima, Gruden, Maja, Anđelković, Katarina, Čobeljić, Božidar, Zlatar, Matija, "Synthesis and characterization of Fe(III) and Mn(II) complexes with condensation product of thiosemicarbazide and 2-acetylthiazole" in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine (2022):126, https://hdl.handle.net/21.15107/rcub_cer_5080 .