Two Co(III) complexes [Co(L1)2]BF4·H2O (1) and [Co(L2)(N3)3] (2) with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1) and the condensation product of 2-acetylpyridine and Girard’s P reagent (HL2Cl) and Co(BF4)2·6H2O have been synthesized. Complexes were characterized by elemental analysis, IR and NMR spectroscopy and X-ray crystallographic analysis. DFT calculations revealed the thermodynamical stability of obtained complexes.
Kompleks [Co(L1)2]BF4·H2O (1) dobijen je u reakciji Co(BF4)2·6H2O sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola (HL1), dok je kompleks [Co(L2)(N3)3] (2) dobijen u reakciji iste soli sa kondenzacionim proizvodom 2-acetilpiridina i Žirarovog P reagensa (HL2Cl). Oba kompleksa su okarakterisana elementalnom analizom, IC i NMR spektroskopijom i rendgenskom strukturnom analizom. DFT proračunima određena je termodinamička stabilnost kompleksa.
Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine, 2022, 113-
TY - CONF
AU - Čobeljić, Božidar
AU - Savić, Milica
AU - Jevtović, Mima
AU - Mitić, Dragana
AU - Zlatar, Matija
AU - Gruden, Maja
AU - Anđelković, Katarina
PY - 2022
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/5079
AB - Two Co(III) complexes [Co(L1)2]BF4·H2O (1) and [Co(L2)(N3)3] (2) with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1) and the condensation product of 2-acetylpyridine and Girard’s P reagent (HL2Cl) and Co(BF4)2·6H2O have been synthesized. Complexes were characterized by elemental analysis, IR and NMR spectroscopy and X-ray crystallographic analysis. DFT calculations revealed the thermodynamical stability of obtained complexes.
AB - Kompleks [Co(L1)2]BF4·H2O (1) dobijen je u reakciji Co(BF4)2·6H2O sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola (HL1), dok je kompleks [Co(L2)(N3)3] (2) dobijen u reakciji iste soli sa kondenzacionim proizvodom 2-acetilpiridina i Žirarovog P reagensa (HL2Cl). Oba kompleksa su okarakterisana elementalnom analizom, IC i NMR spektroskopijom i rendgenskom strukturnom analizom. DFT proračunima određena je termodinamička stabilnost kompleksa.
PB - Belgrade : Serbian Chemical Society
C3 - Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
T1 - Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes
T1 - Ispitivanje koordinacionih sposobnosti NNO i NNS Šifovih baza kao liganada u kompleksima Co(III)
SP - 113
UR - https://hdl.handle.net/21.15107/rcub_cer_5079
ER -
@conference{
author = "Čobeljić, Božidar and Savić, Milica and Jevtović, Mima and Mitić, Dragana and Zlatar, Matija and Gruden, Maja and Anđelković, Katarina",
year = "2022",
abstract = "Two Co(III) complexes [Co(L1)2]BF4·H2O (1) and [Co(L2)(N3)3] (2) with condensation product of thiosemicarbazide and 2-acetylthiazole (HL1) and the condensation product of 2-acetylpyridine and Girard’s P reagent (HL2Cl) and Co(BF4)2·6H2O have been synthesized. Complexes were characterized by elemental analysis, IR and NMR spectroscopy and X-ray crystallographic analysis. DFT calculations revealed the thermodynamical stability of obtained complexes., Kompleks [Co(L1)2]BF4·H2O (1) dobijen je u reakciji Co(BF4)2·6H2O sa kondenzacionim proizvodom tiosemikarbazida i 2-acetiltiazola (HL1), dok je kompleks [Co(L2)(N3)3] (2) dobijen u reakciji iste soli sa kondenzacionim proizvodom 2-acetilpiridina i Žirarovog P reagensa (HL2Cl). Oba kompleksa su okarakterisana elementalnom analizom, IC i NMR spektroskopijom i rendgenskom strukturnom analizom. DFT proračunima određena je termodinamička stabilnost kompleksa.",
publisher = "Belgrade : Serbian Chemical Society",
journal = "Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine",
title = "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes, Ispitivanje koordinacionih sposobnosti NNO i NNS Šifovih baza kao liganada u kompleksima Co(III)",
pages = "113",
url = "https://hdl.handle.net/21.15107/rcub_cer_5079"
}
Čobeljić, B., Savić, M., Jevtović, M., Mitić, D., Zlatar, M., Gruden, M.,& Anđelković, K.. (2022). Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine
Belgrade : Serbian Chemical Society., 113.
https://hdl.handle.net/21.15107/rcub_cer_5079
Čobeljić B, Savić M, Jevtović M, Mitić D, Zlatar M, Gruden M, Anđelković K. Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes. in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine. 2022;:113.
https://hdl.handle.net/21.15107/rcub_cer_5079 .
Čobeljić, Božidar, Savić, Milica, Jevtović, Mima, Mitić, Dragana, Zlatar, Matija, Gruden, Maja, Anđelković, Katarina, "Coordination preferences of NNO and NNS Schiff base ligands with Co(III) complexes" in Book of Abstracts, Proceedings - 58th Meeting of the Serbian Chemical Society, Belgrade, Serbia, June 9-10, 2022 / Kratki izvodi radova, kjniga radova - 58. Savetovanje Srpskog hemijskog društva, Beograd 9. i 10. jun 2022. godine (2022):113,
https://hdl.handle.net/21.15107/rcub_cer_5079 .
,