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The effect of the concentration of the reacting ion on the control of the electrodeposition process

Uticaj koncentracije reagujućeg jona na kontrolu procesa elektrohemijskog taloženja

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2009
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Authors
Živković, Predrag M.
Nikolić, Nebojša D.
Gvozdenović, Milica M.
Popov, Konstantin I.
Article (Published version)
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Abstract
The effect of the concentration of the reacting ion on the nature of the control of the electrodeposition process was investigated by digital simulation of the polarization curve using the Newman form of the polarization curve equation and the Levich dependence of the limiting diffusion current density under natural convection conditions. A simple method for the determination of the exchange current density from polarization measurements is also proposed. The agreement with experiments was correct.
U radu je ispitivan uticaj koncentracije reagujućeg jona na vrstu kontrole procesa elektrohemijskog taloženja. Primenjena je digitalna simulacija polarizacionih krivih na osnovu Newman-ovog oblika jednačine polarizacione krive i Levich-eve zavisnosti granične difuzione gustine struje u uslovima prirodne konvekcije. Predložen je jednostavan metod određivanja gustine struje izmene na osnovu polarizacionih merenja. Dobijena je zadovoljavajuća saglasnost sa eksperimentalno dobijenim vrednostima.
Keywords:
polarization curve equation / concentration dependence
Source:
Journal of the Serbian Chemical Society, 2009, 74, 3, 291-299
Publisher:
  • Serbian Chemical Society
Projects:
  • Deposition of ultrafinepowders of metals and alloys and nanostructured surfaces by electrochemical techniques (RS-142032)

DOI: 10.2298/JSC0903291Z

ISSN: 0352-5139

WoS: 000264850000007

Scopus: 2-s2.0-68949083695
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URI
http://cer.ihtm.bg.ac.rs/handle/123456789/503
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