The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution
Zeolit NaX kao templat za dobijanje monoatomski dispergovane platine impregnacijom sa rastvorom Pt(II)-acetilacetonata u acetonu
Abstract
The incorporation of platinum into the cavities of NaX zeolite was realized by impregnation and thermal decomposition of the organometallic compound Pt(II)-acetylacetonate dissolved in acetone. A high dispersion of platinum to predominantly mono-atomic particles was achieved thanks to the tight fit of the Pt(II)-acetylacetonate molecules in the aperture of the zeolite supercage. Using the high angle annular dark field imaging technique of HRTEM, individual Pt particles situated within the zeolite crystals were, for the first time, clearly visible. This offers new possibilities of studying the distribution of incorporated metal particles along the crystal depth.
Platina je ugrađena u kaveze zeolita NaX impregnacijom i termalnim razlaganjem organometalnog jedinjenja Pt(II)-acetilacetonata, rastvrenog u acetonu. Visoka disperznost platine pretežno u vidu jednoatomnih čestica, postignuta je zahvaljujući bliskosti dimenzija molekule Pt(II)-acetilacetonata i prečnika ulaznog otvora supekaveza zeolita. Tehnikom širokougaone difrakcije i tamnog polja ultravisokorezolutivne elektronske mikroskopije, prvi put su učinjene vidljivim individualne čestice platine smeštene unutar kristala zeolita, što otvara nove mogućnosti u proučavanju raspodele ugrađenih metalnih čestica po dubini kristala.
Keywords:
HRTEM imaging / impregnation technique / NaX zeolite / Pt(II)-acetylacetonate / platinum-modified zeoliteSource:
Journal of the Serbian Chemical Society, 2009, 74, 10, 1113-1123Publisher:
- Serbian Chemical Society
Funding / projects:
- Struktura, termodinamičke i elektrohemijske osobine materijala za konverziju energije i nove tehnologije (RS-142047)
DOI: 10.2298/JSC0910113M
ISSN: 0352-5139
WoS: 000270746600010
Scopus: 2-s2.0-77349116650
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Institution/Community
IHTMTY - JOUR AU - Mentus, Slavko AU - Mojović, Zorica AU - Radmilović, Velimir R. PY - 2009 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/499 AB - The incorporation of platinum into the cavities of NaX zeolite was realized by impregnation and thermal decomposition of the organometallic compound Pt(II)-acetylacetonate dissolved in acetone. A high dispersion of platinum to predominantly mono-atomic particles was achieved thanks to the tight fit of the Pt(II)-acetylacetonate molecules in the aperture of the zeolite supercage. Using the high angle annular dark field imaging technique of HRTEM, individual Pt particles situated within the zeolite crystals were, for the first time, clearly visible. This offers new possibilities of studying the distribution of incorporated metal particles along the crystal depth. AB - Platina je ugrađena u kaveze zeolita NaX impregnacijom i termalnim razlaganjem organometalnog jedinjenja Pt(II)-acetilacetonata, rastvrenog u acetonu. Visoka disperznost platine pretežno u vidu jednoatomnih čestica, postignuta je zahvaljujući bliskosti dimenzija molekule Pt(II)-acetilacetonata i prečnika ulaznog otvora supekaveza zeolita. Tehnikom širokougaone difrakcije i tamnog polja ultravisokorezolutivne elektronske mikroskopije, prvi put su učinjene vidljivim individualne čestice platine smeštene unutar kristala zeolita, što otvara nove mogućnosti u proučavanju raspodele ugrađenih metalnih čestica po dubini kristala. PB - Serbian Chemical Society T2 - Journal of the Serbian Chemical Society T1 - The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution T1 - Zeolit NaX kao templat za dobijanje monoatomski dispergovane platine impregnacijom sa rastvorom Pt(II)-acetilacetonata u acetonu VL - 74 IS - 10 SP - 1113 EP - 1123 DO - 10.2298/JSC0910113M ER -
@article{ author = "Mentus, Slavko and Mojović, Zorica and Radmilović, Velimir R.", year = "2009", abstract = "The incorporation of platinum into the cavities of NaX zeolite was realized by impregnation and thermal decomposition of the organometallic compound Pt(II)-acetylacetonate dissolved in acetone. A high dispersion of platinum to predominantly mono-atomic particles was achieved thanks to the tight fit of the Pt(II)-acetylacetonate molecules in the aperture of the zeolite supercage. Using the high angle annular dark field imaging technique of HRTEM, individual Pt particles situated within the zeolite crystals were, for the first time, clearly visible. This offers new possibilities of studying the distribution of incorporated metal particles along the crystal depth., Platina je ugrađena u kaveze zeolita NaX impregnacijom i termalnim razlaganjem organometalnog jedinjenja Pt(II)-acetilacetonata, rastvrenog u acetonu. Visoka disperznost platine pretežno u vidu jednoatomnih čestica, postignuta je zahvaljujući bliskosti dimenzija molekule Pt(II)-acetilacetonata i prečnika ulaznog otvora supekaveza zeolita. Tehnikom širokougaone difrakcije i tamnog polja ultravisokorezolutivne elektronske mikroskopije, prvi put su učinjene vidljivim individualne čestice platine smeštene unutar kristala zeolita, što otvara nove mogućnosti u proučavanju raspodele ugrađenih metalnih čestica po dubini kristala.", publisher = "Serbian Chemical Society", journal = "Journal of the Serbian Chemical Society", title = "The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution, Zeolit NaX kao templat za dobijanje monoatomski dispergovane platine impregnacijom sa rastvorom Pt(II)-acetilacetonata u acetonu", volume = "74", number = "10", pages = "1113-1123", doi = "10.2298/JSC0910113M" }
Mentus, S., Mojović, Z.,& Radmilović, V. R.. (2009). The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution. in Journal of the Serbian Chemical Society Serbian Chemical Society., 74(10), 1113-1123. https://doi.org/10.2298/JSC0910113M
Mentus S, Mojović Z, Radmilović VR. The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution. in Journal of the Serbian Chemical Society. 2009;74(10):1113-1123. doi:10.2298/JSC0910113M .
Mentus, Slavko, Mojović, Zorica, Radmilović, Velimir R., "The use of NaX zeolite as a template to obtain a mono-atomic pt dispersion by impregnation with Pt(II) acetylacetonate/acetone solution" in Journal of the Serbian Chemical Society, 74, no. 10 (2009):1113-1123, https://doi.org/10.2298/JSC0910113M . .