Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions
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In the era of pollution and hazardous materials, new methods for the detection of pollutants
in the environment are urgently needed. Due to their specific features such as
photoluminescence (PL) in the visible part of the spectrum, dispersibility in water, and
organic solvents, nontoxicity, and biocompatibility, graphene quantum dots (GQDs) attract
attention in optical sensing of various ions and molecules. In this study, pristine graphene
quantum dots (p-GQDs) were produced in a simple single-step electrochemical top-down
approach using graphite electrodes as a starting material, and dispersion of sodium-hydroxide in 96% ethanol as a medium for electrochemical reaction. These p-GQDs were
gamma-irradiated in a dose of 25 kGy in presence of ethylenediamine in Ar medium to
introduce amino groups in their crystal lattice. Results obtained from AFM microscopy
indicate the height-uniformity of irradiated GQDs. The presence of amino groups in GQDs
was confirmed by FTIR, XPS, and UV...-Vis spectroscopies. According to results obtained
from PL spectroscopy, a significant narrowing of emission band in irradiated GQDs was
observed. In further research, these GQDs were investigated as a potential PL sensor for iron
which is one of the most abundant heavy metal in the environment. In the preliminary
investigation, a water dispersion of irradiated GQDs was mixed with Fe(III) solution in
concentrations of 50 and 100 µM. Using a PL spectroscopy the PL intensity of irradiated
GQDs in presence of Fe (III) was measured. From the obtained results, it can be seen that
Fe(III) ions lead to quenching of GQDs PL intensity. Then, PL intensities were measured in
presence of Fe(III) ions in concentration range 0-100 µM. With an increase of Fe(III)
concentration, the PL intensity of GQDs decreased. It can be concluded that gamma-irradiated amino-doped GQDs have significant potential in the so-called ,,turn of“ detection
of Fe(III) ions in the aqueous medium
Ključne reči:
Graphene Quantum Dots / Fe(III)Izvor:
Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering, 2021, 35-35Izdavač:
- Belgrade, Serbia : Institute of Technical Sciences of SASA
Finansiranje / projekti:
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200026 (Univerzitet u Beogradu, Institut za hemiju, tehnologiju i metalurgiju - IHTM) (RS-MESTD-inst-2020-200026)
- Ministarstvo nauke, tehnološkog razvoja i inovacija Republike Srbije, institucionalno finansiranje - 200017 (Univerzitet u Beogradu, Institut za nuklearne nauke Vinča, Beograd-Vinča) (RS-MESTD-inst-2020-200017)
Napomena:
- Nineteenth Young Researchers’ Conference - Materials Science and Engineering: December 1-3, 2021, Belgrade, Serbia
Institucija/grupa
IHTMTY - CONF AU - Dorontić, Slađana AU - Marković, Olivera AU - Kleut, Duška AU - Jovanović, Svetlana PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4890 AB - In the era of pollution and hazardous materials, new methods for the detection of pollutants in the environment are urgently needed. Due to their specific features such as photoluminescence (PL) in the visible part of the spectrum, dispersibility in water, and organic solvents, nontoxicity, and biocompatibility, graphene quantum dots (GQDs) attract attention in optical sensing of various ions and molecules. In this study, pristine graphene quantum dots (p-GQDs) were produced in a simple single-step electrochemical top-down approach using graphite electrodes as a starting material, and dispersion of sodium-hydroxide in 96% ethanol as a medium for electrochemical reaction. These p-GQDs were gamma-irradiated in a dose of 25 kGy in presence of ethylenediamine in Ar medium to introduce amino groups in their crystal lattice. Results obtained from AFM microscopy indicate the height-uniformity of irradiated GQDs. The presence of amino groups in GQDs was confirmed by FTIR, XPS, and UV-Vis spectroscopies. According to results obtained from PL spectroscopy, a significant narrowing of emission band in irradiated GQDs was observed. In further research, these GQDs were investigated as a potential PL sensor for iron which is one of the most abundant heavy metal in the environment. In the preliminary investigation, a water dispersion of irradiated GQDs was mixed with Fe(III) solution in concentrations of 50 and 100 µM. Using a PL spectroscopy the PL intensity of irradiated GQDs in presence of Fe (III) was measured. From the obtained results, it can be seen that Fe(III) ions lead to quenching of GQDs PL intensity. Then, PL intensities were measured in presence of Fe(III) ions in concentration range 0-100 µM. With an increase of Fe(III) concentration, the PL intensity of GQDs decreased. It can be concluded that gamma-irradiated amino-doped GQDs have significant potential in the so-called ,,turn of“ detection of Fe(III) ions in the aqueous medium PB - Belgrade, Serbia : Institute of Technical Sciences of SASA C3 - Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering T1 - Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions SP - 35 EP - 35 UR - https://hdl.handle.net/21.15107/rcub_cer_4890 ER -
@conference{ author = "Dorontić, Slađana and Marković, Olivera and Kleut, Duška and Jovanović, Svetlana", year = "2021", abstract = "In the era of pollution and hazardous materials, new methods for the detection of pollutants in the environment are urgently needed. Due to their specific features such as photoluminescence (PL) in the visible part of the spectrum, dispersibility in water, and organic solvents, nontoxicity, and biocompatibility, graphene quantum dots (GQDs) attract attention in optical sensing of various ions and molecules. In this study, pristine graphene quantum dots (p-GQDs) were produced in a simple single-step electrochemical top-down approach using graphite electrodes as a starting material, and dispersion of sodium-hydroxide in 96% ethanol as a medium for electrochemical reaction. These p-GQDs were gamma-irradiated in a dose of 25 kGy in presence of ethylenediamine in Ar medium to introduce amino groups in their crystal lattice. Results obtained from AFM microscopy indicate the height-uniformity of irradiated GQDs. The presence of amino groups in GQDs was confirmed by FTIR, XPS, and UV-Vis spectroscopies. According to results obtained from PL spectroscopy, a significant narrowing of emission band in irradiated GQDs was observed. In further research, these GQDs were investigated as a potential PL sensor for iron which is one of the most abundant heavy metal in the environment. In the preliminary investigation, a water dispersion of irradiated GQDs was mixed with Fe(III) solution in concentrations of 50 and 100 µM. Using a PL spectroscopy the PL intensity of irradiated GQDs in presence of Fe (III) was measured. From the obtained results, it can be seen that Fe(III) ions lead to quenching of GQDs PL intensity. Then, PL intensities were measured in presence of Fe(III) ions in concentration range 0-100 µM. With an increase of Fe(III) concentration, the PL intensity of GQDs decreased. It can be concluded that gamma-irradiated amino-doped GQDs have significant potential in the so-called ,,turn of“ detection of Fe(III) ions in the aqueous medium", publisher = "Belgrade, Serbia : Institute of Technical Sciences of SASA", journal = "Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering", title = "Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions", pages = "35-35", url = "https://hdl.handle.net/21.15107/rcub_cer_4890" }
Dorontić, S., Marković, O., Kleut, D.,& Jovanović, S.. (2021). Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions. in Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering Belgrade, Serbia : Institute of Technical Sciences of SASA., 35-35. https://hdl.handle.net/21.15107/rcub_cer_4890
Dorontić S, Marković O, Kleut D, Jovanović S. Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions. in Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering. 2021;:35-35. https://hdl.handle.net/21.15107/rcub_cer_4890 .
Dorontić, Slađana, Marković, Olivera, Kleut, Duška, Jovanović, Svetlana, "Graphene quantum dots with amino groups as a potential photoluminescent probe for Fe(III) ions" in Program and the Book of Abstracts - Nineteenth Young Researchers Conference – Materials Science and Engineering (2021):35-35, https://hdl.handle.net/21.15107/rcub_cer_4890 .