Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries
Authors
Senćanski, Jelena
Nikolić, Nenad

Nedić, Zoran
Maksimović, Jelena

Blagojević, Stevan

Pagnacco, Maja

Article (Accepted Version)

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Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemic...al behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.
Keywords:
Natural Pigment from Madder Plant / Eco-Friendly Cathode Material / Aqueous Li and Na-Ion BatteriesSource:
Journal of Electrochemical Society, 2021, 168, 10, 100535-Publisher:
- IOP Publishing
Funding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200051 (Institute of General and Physical Chemistry, Belgrade) (RS-200051)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200053 (University of Belgrade, Institute for Multidisciplinary Research) (RS-200053)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
Note:
- This is the peer-reviewed version of the article: Senćanski, Jelena, Nikolić, Nenad, Nedić, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of Electrochemical Society, 168, no. 10 (2021):100535, https://doi.org/10.1149/1945-7111/ac3043
- Published version: https://cer.ihtm.bg.ac.rs/handle/123456789/4839
Related info:
- Version of
https://cer.ihtm.bg.ac.rs/handle/123456789/4839 - Version of
https://doi.org/10.1149/1945-7111/ac3043
DOI: 10.1149/1945-7111/ac3043
ISSN: 1945-7111; 0013-4651
WoS: 000711650500001
Scopus: 2-s2.0-85118880927
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IHTMTY - JOUR AU - Senćanski, Jelena AU - Nikolić, Nenad AU - Nedić, Zoran AU - Maksimović, Jelena AU - Blagojević, Stevan AU - Pagnacco, Maja PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4860 AB - Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail. PB - IOP Publishing T2 - Journal of Electrochemical Society T1 - Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries VL - 168 IS - 10 SP - 100535 DO - 10.1149/1945-7111/ac3043 ER -
@article{ author = "Senćanski, Jelena and Nikolić, Nenad and Nedić, Zoran and Maksimović, Jelena and Blagojević, Stevan and Pagnacco, Maja", year = "2021", abstract = "Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.", publisher = "IOP Publishing", journal = "Journal of Electrochemical Society", title = "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries", volume = "168", number = "10", pages = "100535", doi = "10.1149/1945-7111/ac3043" }
Senćanski, J., Nikolić, N., Nedić, Z., Maksimović, J., Blagojević, S.,& Pagnacco, M.. (2021). Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society IOP Publishing., 168(10), 100535. https://doi.org/10.1149/1945-7111/ac3043
Senćanski J, Nikolić N, Nedić Z, Maksimović J, Blagojević S, Pagnacco M. Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society. 2021;168(10):100535. doi:10.1149/1945-7111/ac3043 .
Senćanski, Jelena, Nikolić, Nenad, Nedić, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of Electrochemical Society, 168, no. 10 (2021):100535, https://doi.org/10.1149/1945-7111/ac3043 . .