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Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries

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2021
ACC_Sencanski+et+al_2021_J._Electrochem._Soc._10.1149_1945-7111_ac3043.pdf (1.528Mb)
Authors
Senćanski, Jelena
Nikolić, Nenad
Nedić, Zoran
Maksimović, Jelena
Blagojević, Stevan
Pagnacco, Maja
Article (Accepted Version)
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Abstract
Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemic...al behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.

Keywords:
Natural Pigment from Madder Plant / Eco-Friendly Cathode Material / Aqueous Li and Na-Ion Batteries
Source:
Journal of Electrochemical Society, 2021, 168, 10, 100535-
Publisher:
  • IOP Publishing
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200051 (Institute of General and Physical Chemistry, Belgrade) (RS-200051)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200053 (University of Belgrade, Institute for Multidisciplinary Research) (RS-200053)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200146 (University of Belgrade, Faculty of Physical Chemistry) (RS-200146)
Note:
  • This is the peer-reviewed version of the article: Senćanski, Jelena, Nikolić, Nenad, Nedić, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of Electrochemical Society, 168, no. 10 (2021):100535, https://doi.org/10.1149/1945-7111/ac3043
  • Published version: https://cer.ihtm.bg.ac.rs/handle/123456789/4839
Related info:
  • Version of
    https://cer.ihtm.bg.ac.rs/handle/123456789/4839
  • Version of
    https://doi.org/10.1149/1945-7111/ac3043

DOI: 10.1149/1945-7111/ac3043

ISSN: 1945-7111; 0013-4651

WoS: 000711650500001

Scopus: 2-s2.0-85118880927
[ Google Scholar ]
1
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4860
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Senćanski, Jelena
AU  - Nikolić, Nenad
AU  - Nedić, Zoran
AU  - Maksimović, Jelena
AU  - Blagojević, Stevan
AU  - Pagnacco, Maja
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4860
AB  - Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.
PB  - IOP Publishing
T2  - Journal of Electrochemical Society
T1  - Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries
VL  - 168
IS  - 10
SP  - 100535
DO  - 10.1149/1945-7111/ac3043
ER  - 
@article{
author = "Senćanski, Jelena and Nikolić, Nenad and Nedić, Zoran and Maksimović, Jelena and Blagojević, Stevan and Pagnacco, Maja",
year = "2021",
abstract = "Modifying commercial Li-ion batteries to become more environmentally friendly is of a growing concern. This paper provides anexamination of a potential replacement for commercial cathode material using a naturally occurring purpurin in aqueous solutions oflithium and sodium salts. The purpurin is extracted from the Madder plant (Rubia tinctorum) and characterized through XRPD, FTIR,and SEM methods. The intercalation and de-intercalation capacities obtained for the purpurin as a cathode material in the aqueoussolution of LiNO3 are approximately 40 mAh g−1. Compared to the capacity of ∼35 mAh g−1 obtained for commercially usedtransition metal oxides in an aqueous solution of Li salt, results presented make the purpurin a promising material for the “green”development of Li-ion batteries. Although the initial purpurin capacity in NaNO3 solution is almost doubled (∼73 mA h g−1)compared to that of Li-salt, it is unstable and fades during cycling. The possible explanation of the electrochemical behavior ofpurpurin as the cathode material in aqueous solutions of Li and Na salts is discussed in detail.",
publisher = "IOP Publishing",
journal = "Journal of Electrochemical Society",
title = "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries",
volume = "168",
number = "10",
pages = "100535",
doi = "10.1149/1945-7111/ac3043"
}
Senćanski, J., Nikolić, N., Nedić, Z., Maksimović, J., Blagojević, S.,& Pagnacco, M.. (2021). Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society
IOP Publishing., 168(10), 100535.
https://doi.org/10.1149/1945-7111/ac3043
Senćanski J, Nikolić N, Nedić Z, Maksimović J, Blagojević S, Pagnacco M. Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries. in Journal of Electrochemical Society. 2021;168(10):100535.
doi:10.1149/1945-7111/ac3043 .
Senćanski, Jelena, Nikolić, Nenad, Nedić, Zoran, Maksimović, Jelena, Blagojević, Stevan, Pagnacco, Maja, "Natural Pigment from Madder Plant as an Eco-Friendly Cathode Material for Aqueous Li and Na-Ion Batteries" in Journal of Electrochemical Society, 168, no. 10 (2021):100535,
https://doi.org/10.1149/1945-7111/ac3043 . .

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