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dc.creatorBanković, Predrag
dc.creatorMilutinović Nikolić, Aleksandra
dc.creatorMojović, Zorica
dc.creatorRosić, Aleksandra
dc.creatorČupić, Željko
dc.creatorLončarević, Davor
dc.creatorJovanović, Dušan M.
dc.date.accessioned2019-01-30T17:19:13Z
dc.date.available2019-01-30T17:19:13Z
dc.date.issued2009
dc.identifier.issn0253-9837
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/484
dc.description.abstractThe catalytic wet peroxide oxidation (CWPO) of toluene on two bentonite-based AlFe-pillared clays (PILCs) with different iron contents was investigated. The PILCs were obtained using bentonite clay from Bogovina, Serbia. The change in chemical and phase composition and textural properties of the starting clay and synthesized catalysts was monitored using X-ray diffraction, inductively coupled plasma optical emission spectrometry, UV-Vis diffuse reflectance spectrometry, and physisorption of nitrogen. The catalytic performance was examined using gas chromatography. The Na-exchange process lowered the (001) smectite basal plane spacing, but the clay retained its swelling properties, while the pillaring process increased it. The surface areas of both synthesized pillared clays increased to similar values although their Fe content was different. At 37 degrees C, both catalysts show significant toluene degradation, with the one richer in Fe having higher efficiency. The leaching of the active cations during reaction was negligible, and the catalysts were stable. AlFe-pillared clay catalysts can be used in CWPO for the elimination of BTEX compounds from plant effluent streams.en
dc.publisherScience Press, Beijing
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142019/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/166001/RS//
dc.rightsrestrictedAccess
dc.sourceChinese Journal of Catalysis
dc.subjectcatalytic wet peroxide oxidationen
dc.subjecthydrogen peroxideen
dc.subjectpillared interlayered clayen
dc.subjecttolueneen
dc.subjectwater treatmenten
dc.titleToluene Degradation in Water Using AlFe-Pillared Clay Catalystsen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractЛончаревић, Давор; Банковић, Предраг; Росиц, Aлександра; Мојовић, Зорица; Јовановиц, Дусан; Милутиновић Николић, Aлександра; Чупић, Жељко;
dc.citation.volume30
dc.citation.issue1
dc.citation.spage14
dc.citation.epage18
dc.citation.other30(1): 14-18
dc.citation.rankM22
dc.identifier.doi10.1016/S1872-2067(08)60086-8
dc.identifier.rcubConv_2435
dc.identifier.scopus2-s2.0-60549095955
dc.identifier.wos000263444300005
dc.type.versionpublishedVersion


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