Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions
Само за регистроване кориснике
2021
Аутори
Milošević, Dragana
Lević, Steva
Lazarević, Slavica

Veličković, Zlate

Marinković, Aleksandar D.

Petrović, Rada

Petrović, Predrag
Чланак у часопису (Објављена верзија)

Метаподаци
Приказ свих података о документуАпстракт
The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pHPZC. The adsorption performances of Sa and Sa-HAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g−1, while for Sa-HAp were 79.55, 52.59 and 45.01 mg g−1, respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 ...M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent.
Кључне речи:
Adsorption mechanism / Batch and column adsorption / Hydroxyapatite / Kinetic and adsorption studyИзвор:
Journal of Environmental Management, 2021, 297, 113358-Издавач:
- Elsevier
Финансирање / пројекти:
- Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200026 (Универзитет у Београду, Институт за хемију, технологију и металургију - ИХТМ) (RS-200026)
- Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200116 (Универзитет у Београду, Пољопривредни факултет) (RS-200116)
- Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200135 (Универзитет у Београду, Технолошко-металуршки факултет) (RS-200135)
- Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 200287 (Иновациони центар Технолошко-металуршког факултета у Београду доо) (RS-200287)
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 213-1/21-08-03-2021
DOI: 10.1016/j.jenvman.2021.113358
ISSN: 0301-4797; 1095-8630
PubMed: 34311248
WoS: 000691262000002
Scopus: 2-s2.0-85111070525
Институција/група
IHTMTY - JOUR AU - Milošević, Dragana AU - Lević, Steva AU - Lazarević, Slavica AU - Veličković, Zlate AU - Marinković, Aleksandar D. AU - Petrović, Rada AU - Petrović, Predrag PY - 2021 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4811 AB - The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pHPZC. The adsorption performances of Sa and Sa-HAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g−1, while for Sa-HAp were 79.55, 52.59 and 45.01 mg g−1, respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent. PB - Elsevier T2 - Journal of Environmental Management T1 - Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions VL - 297 SP - 113358 DO - 10.1016/j.jenvman.2021.113358 ER -
@article{ author = "Milošević, Dragana and Lević, Steva and Lazarević, Slavica and Veličković, Zlate and Marinković, Aleksandar D. and Petrović, Rada and Petrović, Predrag", year = "2021", abstract = "The alkali treated subglebal tissue of the mosaic puffball (Handkea utriformis) (Sa) and Sa modified with hydroxyapatite (Sa-HAp), obtained by successive ionic layer adsorption and reaction (SILAR) method, were used for the removal of Pb2+, Cd2+ and Ni2+ from aqueous solution. The materials were characterized by FT-IR, Raman, SEM and EDS analysis and by determination of pHPZC. The adsorption performances of Sa and Sa-HAp were assessed in batch experiments at different pH, contact times, temperatures and mass of the adsorbent. Different models of adsorption isotherms were used, and the best fit was obtained with the Langmuir model. Maximum adsorption capacities of Sa towards Pb2+, Cd2+ and Ni2+ were 44.82, 15.54 and 17.21 mg g−1, while for Sa-HAp were 79.55, 52.59 and 45.01 mg g−1, respectively. Kinetic data were well fitted by a pseudo second-order model, while thermodynamic studies disclose spontaneous and endothermic adsorption process. The Sa-Hap was successfully regenerated with 1 M NaCl and after the fifth desorption cycle and 10 h achieved 82.9, 69.7 and 60.4 %, while for 0.5 M NaCl + 0.5 M NaOH and 1 h was 78.3, 64.1, 57.5 % of desorbed Pb2+, Cd2+ and Ni2+, respectively. The competitive study and results from a column system confirmed good applicability of Sa-HAp adsorbent.", publisher = "Elsevier", journal = "Journal of Environmental Management", title = "Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions", volume = "297", pages = "113358", doi = "10.1016/j.jenvman.2021.113358" }
Milošević, D., Lević, S., Lazarević, S., Veličković, Z., Marinković, A. D., Petrović, R.,& Petrović, P.. (2021). Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions. in Journal of Environmental Management Elsevier., 297, 113358. https://doi.org/10.1016/j.jenvman.2021.113358
Milošević D, Lević S, Lazarević S, Veličković Z, Marinković AD, Petrović R, Petrović P. Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions. in Journal of Environmental Management. 2021;297:113358. doi:10.1016/j.jenvman.2021.113358 .
Milošević, Dragana, Lević, Steva, Lazarević, Slavica, Veličković, Zlate, Marinković, Aleksandar D., Petrović, Rada, Petrović, Predrag, "Hybrid material based on subgleba of mosaic puffball mushroom (Handkea utriformis) as an adsorbent for heavy metal removal from aqueous solutions" in Journal of Environmental Management, 297 (2021):113358, https://doi.org/10.1016/j.jenvman.2021.113358 . .