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dc.creatorStefanović, Ivan
dc.creatorDžunuzović, Jasna
dc.creatorDžunuzović, Enis S.
dc.creatorBrzić, Saša J.
dc.creatorJasiukaityte-Grojzdek, Edita
dc.creatorBasagni, Andrea
dc.creatorMarega, Carla
dc.date.accessioned2021-10-12T13:36:22Z
dc.date.available2021-10-12T13:36:22Z
dc.date.issued2021
dc.identifier.issn0300-9440
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4782
dc.description.abstractA series of novel waterborne polyurethanes (WBPUs) was synthesized using α,ω-dihydroxypropyl poly(dimethylsiloxane) (PDMS), isophorone diisocyanate (IPDI), 2,2-bis-(hydroxymethyl) propionic acid (DMPA) and triethylamine (TEA). Different DMPA/PDMS molar ratio (from 0.2 to 0.7) and fixed –NCO/–OH molar ratio of 1.7, has been applied for the synthesis of six different WBPU films, without utilization of chain extension step during the synthesis. The structure of the prepared WBPUs was examined and confirmed by FTIR and NMR spectroscopy. The particle size of the prepared WBPU dispersions and molecular weight of WBPU films decrease with increasing DMPA content. In order to investigate the effect of the DMPA/PDMS ratio on thermal, mechanical and morphological properties, as well as the water resistance of the prepared WBPUs, diverse experimental techniques, such as thermogravimetric analysis, dynamic mechanical analysis, tensile tests, X-ray diffraction analysis (XRD), atomic force microscopy (AFM), scanning electron microscopy (SEM) and water contact angle measurements have been carried out. This research has shown that the incorporation of PDMS in WBPUs led to the appearance of microphase separation and provided surface hydrophobicity, good thermal and mechanical properties, which allow application of these WBPUs as coatings for various purposes.sr
dc.language.isoensr
dc.publisherElseviersr
dc.relationinfo:eu-repo/grantAgreement/MESTD/inst-2020/200026/RS//sr
dc.rightsrestrictedAccesssr
dc.sourceProgress in Organic Coatingssr
dc.subjectMechanical propertiessr
dc.subjectMorphologysr
dc.subjectPoly(dimethylsiloxane)sr
dc.subjectThermal propertiessr
dc.subjectWaterborne polyurethanesr
dc.titleTailoring the properties of waterborne polyurethanes by incorporating different content of poly(dimethylsiloxane)sr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМарега, Царла; Стефановић, Иван С.; Джунузовић, Јасна В.; Джунузовић, Енис С.; Брзић, Саша Ј.; Јасиукаитyте-Гројздек, Едита; Басагни, Aндреа;
dc.citation.volume161
dc.citation.spage106474
dc.citation.rankaM21~
dc.identifier.doi10.1016/j.porgcoat.2021.106474
dc.identifier.scopus2-s2.0-85113279032
dc.identifier.wos000705545300008
dc.type.versionpublishedVersionsr


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Приказ основних података о документу