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Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®

Authorized Users Only
2021
Authors
Marinović, Sanja
Mudrinić, Tihana
Dojčinović, Biljana
Barudžija, Tanja
Banković, Predrag
Novaković, Tatjana
Article (Published version)
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Abstract
Porous cobalt-doped alumina catalysts were synthetized using the sol-gel method. The synthesized materials were calcined at 500 °C, 1000 °C and 1100 °C and denoted as CoA-500, CoA-1000 and CoA-1100, respectively. Catalysts were characterized using XRPD, H2-TPR and low temperature N2 physisorption techniques. Applied techniques showed that the annealing temperature affects the structural and textural properties of the catalysts. The synthesized catalysts were investigated in the degradation of tartrazine in the presence of Oxone®. The influence of the mass of catalyst, reaction time, reaction temperature and initial pH were investigated. The temperature increase was beneficial for the dye degradation rate. CoA-500 was proved to be the most efficient among the investigated catalysts. The reaction followed the pseudo-first order kinetics for all investigated temperatures for all three catalysts. All cobalt-doped alumina catalysts were found to be efficient in the Oxone® induced catalytic ...degradation of tartrazine with CoA-500 showing the best performance.

Keywords:
Alumina / Catalytic oxidation process / Cobalt-doped catalyst / Oxone® / Sol-gel
Source:
Journal of Environmental Chemical Engineering, 2021, 9, 6, 106348-
Publisher:
  • Elsevier
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200026 (University of Belgrade, Institute of Chemistry, Technology and Metallurgy - IChTM) (RS-200026)

DOI: 10.1016/j.jece.2021.106348

ISSN: 2213-3437

WoS: 000700593300001

Scopus: 2-s2.0-85115033410
[ Google Scholar ]
2
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4762
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Marinović, Sanja
AU  - Mudrinić, Tihana
AU  - Dojčinović, Biljana
AU  - Barudžija, Tanja
AU  - Banković, Predrag
AU  - Novaković, Tatjana
PY  - 2021
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4762
AB  - Porous cobalt-doped alumina catalysts were synthetized using the sol-gel method. The synthesized materials were calcined at 500 °C, 1000 °C and 1100 °C and denoted as CoA-500, CoA-1000 and CoA-1100, respectively. Catalysts were characterized using XRPD, H2-TPR and low temperature N2 physisorption techniques. Applied techniques showed that the annealing temperature affects the structural and textural properties of the catalysts. The synthesized catalysts were investigated in the degradation of tartrazine in the presence of Oxone®. The influence of the mass of catalyst, reaction time, reaction temperature and initial pH were investigated. The temperature increase was beneficial for the dye degradation rate. CoA-500 was proved to be the most efficient among the investigated catalysts. The reaction followed the pseudo-first order kinetics for all investigated temperatures for all three catalysts. All cobalt-doped alumina catalysts were found to be efficient in the Oxone® induced catalytic degradation of tartrazine with CoA-500 showing the best performance.
PB  - Elsevier
T2  - Journal of Environmental Chemical Engineering
T1  - Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®
VL  - 9
IS  - 6
SP  - 106348
DO  - 10.1016/j.jece.2021.106348
ER  - 
@article{
author = "Marinović, Sanja and Mudrinić, Tihana and Dojčinović, Biljana and Barudžija, Tanja and Banković, Predrag and Novaković, Tatjana",
year = "2021",
abstract = "Porous cobalt-doped alumina catalysts were synthetized using the sol-gel method. The synthesized materials were calcined at 500 °C, 1000 °C and 1100 °C and denoted as CoA-500, CoA-1000 and CoA-1100, respectively. Catalysts were characterized using XRPD, H2-TPR and low temperature N2 physisorption techniques. Applied techniques showed that the annealing temperature affects the structural and textural properties of the catalysts. The synthesized catalysts were investigated in the degradation of tartrazine in the presence of Oxone®. The influence of the mass of catalyst, reaction time, reaction temperature and initial pH were investigated. The temperature increase was beneficial for the dye degradation rate. CoA-500 was proved to be the most efficient among the investigated catalysts. The reaction followed the pseudo-first order kinetics for all investigated temperatures for all three catalysts. All cobalt-doped alumina catalysts were found to be efficient in the Oxone® induced catalytic degradation of tartrazine with CoA-500 showing the best performance.",
publisher = "Elsevier",
journal = "Journal of Environmental Chemical Engineering",
title = "Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®",
volume = "9",
number = "6",
pages = "106348",
doi = "10.1016/j.jece.2021.106348"
}
Marinović, S., Mudrinić, T., Dojčinović, B., Barudžija, T., Banković, P.,& Novaković, T.. (2021). Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®. in Journal of Environmental Chemical Engineering
Elsevier., 9(6), 106348.
https://doi.org/10.1016/j.jece.2021.106348
Marinović S, Mudrinić T, Dojčinović B, Barudžija T, Banković P, Novaković T. Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®. in Journal of Environmental Chemical Engineering. 2021;9(6):106348.
doi:10.1016/j.jece.2021.106348 .
Marinović, Sanja, Mudrinić, Tihana, Dojčinović, Biljana, Barudžija, Tanja, Banković, Predrag, Novaković, Tatjana, "Cobalt-doped alumina catalysts in catalytic oxidation of tartrazine induced by Oxone®" in Journal of Environmental Chemical Engineering, 9, no. 6 (2021):106348,
https://doi.org/10.1016/j.jece.2021.106348 . .

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