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Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures

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1992
Authors
Konstantinović, Stanimir
Bugarčić, Zorica
Milosavljević, Slobodan
Schroth, Gerhard
Mihailovíć, Mihailo Lj.
Article (Published version)
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Abstract
The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.
Keywords:
Benzeneselenenyl halides / Cyclofunctionalization / Olefinic alcohols / Regioselectivity
Source:
Liebigs Annalen der Chemie, 1992, 1992, 3, 261-268
Publisher:
  • Wiley

DOI: 10.1002/jlac.199219920145

ISSN: 0170-2041

Scopus: 2-s2.0-84986674880
[ Google Scholar ]
35
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4742
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Konstantinović, Stanimir
AU  - Bugarčić, Zorica
AU  - Milosavljević, Slobodan
AU  - Schroth, Gerhard
AU  - Mihailovíć, Mihailo Lj.
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4742
AB  - The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.
PB  - Wiley
T2  - Liebigs Annalen der Chemie
T1  - Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures
VL  - 1992
IS  - 3
SP  - 261
EP  - 268
DO  - 10.1002/jlac.199219920145
ER  - 
@article{
author = "Konstantinović, Stanimir and Bugarčić, Zorica and Milosavljević, Slobodan and Schroth, Gerhard and Mihailovíć, Mihailo Lj.",
year = "1992",
abstract = "The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.",
publisher = "Wiley",
journal = "Liebigs Annalen der Chemie",
title = "Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures",
volume = "1992",
number = "3",
pages = "261-268",
doi = "10.1002/jlac.199219920145"
}
Konstantinović, S., Bugarčić, Z., Milosavljević, S., Schroth, G.,& Mihailovíć, M. Lj.. (1992). Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures. in Liebigs Annalen der Chemie
Wiley., 1992(3), 261-268.
https://doi.org/10.1002/jlac.199219920145
Konstantinović S, Bugarčić Z, Milosavljević S, Schroth G, Mihailovíć ML. Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures. in Liebigs Annalen der Chemie. 1992;1992(3):261-268.
doi:10.1002/jlac.199219920145 .
Konstantinović, Stanimir, Bugarčić, Zorica, Milosavljević, Slobodan, Schroth, Gerhard, Mihailovíć, Mihailo Lj., "Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures" in Liebigs Annalen der Chemie, 1992, no. 3 (1992):261-268,
https://doi.org/10.1002/jlac.199219920145 . .

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