The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.
TY - JOUR
AU - Konstantinović, Stanimir
AU - Bugarčić, Zorica
AU - Milosavljević, Slobodan
AU - Schroth, Gerhard
AU - Mihailovíć, Mihailo Lj.
PY - 1992
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4742
AB - The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.
PB - Wiley
T2 - Liebigs Annalen der Chemie
T1 - Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures
VL - 1992
IS - 3
SP - 261
EP - 268
DO - 10.1002/jlac.199219920145
ER -
@article{
author = "Konstantinović, Stanimir and Bugarčić, Zorica and Milosavljević, Slobodan and Schroth, Gerhard and Mihailovíć, Mihailo Lj.",
year = "1992",
url = "https://cer.ihtm.bg.ac.rs/handle/123456789/4742",
abstract = "The regioselectivity in cyclofunctionalization of some acyclic olefinic alcohols with benzeneselenenyl halides (PhSeCl and PhSeBr) at different temperatures (−78°C, 0°C and room temperature) is investigated. It has been found that Δ4‐ and Δ5‐ alkenols are converted into five‐ and/or six‐membered cyclic phenyl selenoethers, the yield of which decreases with increasing reaction temperature. PhSeCl has been found to be more efficient than PhSeBr in the cyclization reactions.",
publisher = "Wiley",
journal = "Liebigs Annalen der Chemie",
title = "Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures",
volume = "1992",
number = "3",
pages = "261-268",
doi = "10.1002/jlac.199219920145"
}
Konstantinović, S., Bugarčić, Z., Milosavljević, S., Schroth, G.,& Mihailovíć, M. Lj. (1992). Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures.
Liebigs Annalen der Chemie
Wiley., 1992(3), 261-268.
https://doi.org/10.1002/jlac.199219920145
Konstantinović S, Bugarčić Z, Milosavljević S, Schroth G, Mihailovíć ML. Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures. Liebigs Annalen der Chemie. 1992;1992(3):261-268
Konstantinović Stanimir, Bugarčić Zorica, Milosavljević Slobodan, Schroth Gerhard, Mihailovíć Mihailo Lj., "Regioselectivity in Cyclofunctionalization of Olefinic Alcohols with Benzeneselenenyl Halides at Different Temperatures" Liebigs Annalen der Chemie, 1992, no. 3 (1992):261-268,
https://doi.org/10.1002/jlac.199219920145 .
