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Oxygen reduction on a modified ruthenium electrode

Authorized Users Only
1992
Authors
Anastasijević, Nikola A.
Dimitrijević, Z. M.
Adžić, Radoslav R.
Article (Published version)
Metadata
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Abstract
Oxygen reduction has been studied in alkaline solution on a ruthenium electrode modified by thallium and lead adsorbates. A partially oxidized ruthenium electrode is inactive for oxygen reduction. Thallium and lead adsorbates cause pronounced changes on the ruthenium surface giving rise to a four electron-reduction of oxygen. Disc-ring electrode measurements show a predominant direct four electron-reduction, with a first charge-transfer rate determining step. Mass fractions of various reaction pathways have been calculated and the model explaining a direct four electron-reduction discussed. Once activated, ruthenium retains its activity even in the absence of thallium and lead ions in solution phase.
Keywords:
adatoms / adions / electrocatalysis / oxygen reduction / ruthenium electrode
Source:
Electrochimica Acta, 1992, 37, 3, 457-464
Publisher:
  • Elsevier
Funding / projects:
  • The Research Fund of Serbia, Yugoslavia
  • The National Science Foundation through the Yugoslav-American Fund, Contract No. 764

DOI: 10.1016/0013-4686(92)87036-Y

ISSN: 0013-4686

Scopus: 2-s2.0-0000214587
[ Google Scholar ]
22
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/4733
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Anastasijević, Nikola A.
AU  - Dimitrijević, Z. M.
AU  - Adžić, Radoslav R.
PY  - 1992
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/4733
AB  - Oxygen reduction has been studied in alkaline solution on a ruthenium electrode modified by thallium and lead adsorbates. A partially oxidized ruthenium electrode is inactive for oxygen reduction. Thallium and lead adsorbates cause pronounced changes on the ruthenium surface giving rise to a four electron-reduction of oxygen. Disc-ring electrode measurements show a predominant direct four electron-reduction, with a first charge-transfer rate determining step. Mass fractions of various reaction pathways have been calculated and the model explaining a direct four electron-reduction discussed. Once activated, ruthenium retains its activity even in the absence of thallium and lead ions in solution phase.
PB  - Elsevier
T2  - Electrochimica Acta
T1  - Oxygen reduction on a modified ruthenium electrode
VL  - 37
IS  - 3
SP  - 457
EP  - 464
DO  - 10.1016/0013-4686(92)87036-Y
ER  - 
@article{
author = "Anastasijević, Nikola A. and Dimitrijević, Z. M. and Adžić, Radoslav R.",
year = "1992",
abstract = "Oxygen reduction has been studied in alkaline solution on a ruthenium electrode modified by thallium and lead adsorbates. A partially oxidized ruthenium electrode is inactive for oxygen reduction. Thallium and lead adsorbates cause pronounced changes on the ruthenium surface giving rise to a four electron-reduction of oxygen. Disc-ring electrode measurements show a predominant direct four electron-reduction, with a first charge-transfer rate determining step. Mass fractions of various reaction pathways have been calculated and the model explaining a direct four electron-reduction discussed. Once activated, ruthenium retains its activity even in the absence of thallium and lead ions in solution phase.",
publisher = "Elsevier",
journal = "Electrochimica Acta",
title = "Oxygen reduction on a modified ruthenium electrode",
volume = "37",
number = "3",
pages = "457-464",
doi = "10.1016/0013-4686(92)87036-Y"
}
Anastasijević, N. A., Dimitrijević, Z. M.,& Adžić, R. R.. (1992). Oxygen reduction on a modified ruthenium electrode. in Electrochimica Acta
Elsevier., 37(3), 457-464.
https://doi.org/10.1016/0013-4686(92)87036-Y
Anastasijević NA, Dimitrijević ZM, Adžić RR. Oxygen reduction on a modified ruthenium electrode. in Electrochimica Acta. 1992;37(3):457-464.
doi:10.1016/0013-4686(92)87036-Y .
Anastasijević, Nikola A., Dimitrijević, Z. M., Adžić, Radoslav R., "Oxygen reduction on a modified ruthenium electrode" in Electrochimica Acta, 37, no. 3 (1992):457-464,
https://doi.org/10.1016/0013-4686(92)87036-Y . .

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