The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms.
Keywords:
electric conductivity / homogeneous liquid Bi-HgI2 / bismuth / free metal atoms
Source:
Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 1976, 31, 7, 777-780
TY - JOUR
AU - Šušić, Milenko V.
AU - Mentus, Slavko
PY - 1976
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4708
AB - The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms.
PB - De Gruyter
T2 - Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
T1 - A Conductometric Study of the Bi-HgI2 System
VL - 31
IS - 7
SP - 777
EP - 780
DO - 10.1515/zna-1976-0716
ER -
@article{
author = "Šušić, Milenko V. and Mentus, Slavko",
year = "1976",
url = "https://cer.ihtm.bg.ac.rs/handle/123456789/4708",
abstract = "The electric conductivity of the homogeneous liquid Bi-HgI2 System was measured in the temperature range 260—540 °C for several Bi mole fractions ranging from 0.00 to 0.38. The specific conductivity-composition isotherms are indicative of the occurrence of electronic conductivity also before reaching a bismuth concentration sufficient for a complete conversion of HgI2 into Hg2I2. As the temperature rises the share of electronic conductivity in the total conductivity abruptly increases. Comparing the properties of this system with those of the BiI3-Bi System the conclusion is drawn that electronic conductivity in liquids is due to free metal atoms.",
publisher = "De Gruyter",
journal = "Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences",
title = "A Conductometric Study of the Bi-HgI2 System",
volume = "31",
number = "7",
pages = "777-780",
doi = "10.1515/zna-1976-0716"
}
Šušić, M. V.,& Mentus, S. (1976). A Conductometric Study of the Bi-HgI2 System.
Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences
De Gruyter., 31(7), 777-780.
https://doi.org/10.1515/zna-1976-0716
Šušić MV, Mentus S. A Conductometric Study of the Bi-HgI2 System. Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences. 1976;31(7):777-780
Šušić Milenko V., Mentus Slavko, "A Conductometric Study of the Bi-HgI2 System" Zeitschrift fur Naturforschung - Section A Journal of Physical Sciences, 31, no. 7 (1976):777-780,
https://doi.org/10.1515/zna-1976-0716 .
