The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and hydrogen bonding capacity. Numerical values from 9.58 to 8.10 (cal/cm3)1/2 were obtained independently from measurements in hydrocarbon and oxygen containing solvents, close to solubility parameters calculated from polymer densities and molar attraction constants. The values obtained reflects the increasing paraffinic character within the series and can be correlated to solubility parameters published in the literature for structurally similar poly(alkyl acrylates) and poly(alkyl methacrylates).
Keywords:
Cohesive energy densities / poly(di‐n‐alkyl itaconates) / homologous series of poly(di‐n‐alkyl itaconates) / hydrogen bonding capacity / poly(alkyl acrylates) / poly(alkyl methacrylates)
Source:
Die Angewandte Makromolekulare Chemie, 1977, 57, 1, 139-152
Publisher:
Wiley
Funding / projects:
The Scientific Research Fund of the Socialist Republic of Serbia
TY - JOUR
AU - Veličković, Jovan S.
AU - Filipović, Jovanka M.
PY - 1977
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4705
AB - The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and hydrogen bonding capacity. Numerical values from 9.58 to 8.10 (cal/cm3)1/2 were obtained independently from measurements in hydrocarbon and oxygen containing solvents, close to solubility parameters calculated from polymer densities and molar attraction constants. The values obtained reflects the increasing paraffinic character within the series and can be correlated to solubility parameters published in the literature for structurally similar poly(alkyl acrylates) and poly(alkyl methacrylates).
PB - Wiley
T2 - Die Angewandte Makromolekulare Chemie
T1 - Cohesive energy densities of poly(di‐n‐alkyl itaconates)
VL - 57
IS - 1
SP - 139
EP - 152
DO - 10.1002/apmc.1977.050570111
ER -
@article{
author = "Veličković, Jovan S. and Filipović, Jovanka M.",
year = "1977",
abstract = "The solubility parameters of the first ten members of the homologous series of poly(di‐n‐alkyl itaconates) were determined from limiting viscosity numbers in various organic solvents, differing in structure, polarity and hydrogen bonding capacity. Numerical values from 9.58 to 8.10 (cal/cm3)1/2 were obtained independently from measurements in hydrocarbon and oxygen containing solvents, close to solubility parameters calculated from polymer densities and molar attraction constants. The values obtained reflects the increasing paraffinic character within the series and can be correlated to solubility parameters published in the literature for structurally similar poly(alkyl acrylates) and poly(alkyl methacrylates).",
publisher = "Wiley",
journal = "Die Angewandte Makromolekulare Chemie",
title = "Cohesive energy densities of poly(di‐n‐alkyl itaconates)",
volume = "57",
number = "1",
pages = "139-152",
doi = "10.1002/apmc.1977.050570111"
}
Veličković, J. S.,& Filipović, J. M.. (1977). Cohesive energy densities of poly(di‐n‐alkyl itaconates). in Die Angewandte Makromolekulare Chemie
Wiley., 57(1), 139-152.
https://doi.org/10.1002/apmc.1977.050570111
Veličković JS, Filipović JM. Cohesive energy densities of poly(di‐n‐alkyl itaconates). in Die Angewandte Makromolekulare Chemie. 1977;57(1):139-152.
doi:10.1002/apmc.1977.050570111 .
Veličković, Jovan S., Filipović, Jovanka M., "Cohesive energy densities of poly(di‐n‐alkyl itaconates)" in Die Angewandte Makromolekulare Chemie, 57, no. 1 (1977):139-152,
https://doi.org/10.1002/apmc.1977.050570111 . .
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