The title compound, C15H15NO2S3, exists in a bicyclic form, with resonance contributions from two monocyclic forms, each without a second S - S bond. The trithiapentalene heterocyclic ring system is planar, with a mean deviation of 0.014 (2) Å from the mean plane, and is inclined to the plane of the attached phenyl ring at an angle of 17.24 (7)°.
Keywords:
Crystal Structure / S - S interaction / Crystallography
TY - JOUR
AU - Marković, Rade
AU - Rašović, Aleksandar
AU - Steel, Peter
PY - 2008
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/470
AB - The title compound, C15H15NO2S3, exists in a bicyclic form, with resonance contributions from two monocyclic forms, each without a second S - S bond. The trithiapentalene heterocyclic ring system is planar, with a mean deviation of 0.014 (2) Å from the mean plane, and is inclined to the plane of the attached phenyl ring at an angle of 17.24 (7)°.
PB - International Union of Crystallography
T2 - Acta Crystallographica Section E: Structure Reports Online
T1 - Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate
VL - 64
IS - 1
DO - 10.1107/S1600536807063209
ER -
@article{
author = "Marković, Rade and Rašović, Aleksandar and Steel, Peter",
year = "2008",
abstract = "The title compound, C15H15NO2S3, exists in a bicyclic form, with resonance contributions from two monocyclic forms, each without a second S - S bond. The trithiapentalene heterocyclic ring system is planar, with a mean deviation of 0.014 (2) Å from the mean plane, and is inclined to the plane of the attached phenyl ring at an angle of 17.24 (7)°.",
publisher = "International Union of Crystallography",
journal = "Acta Crystallographica Section E: Structure Reports Online",
title = "Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate",
volume = "64",
number = "1",
doi = "10.1107/S1600536807063209"
}
Marković, R., Rašović, A.,& Steel, P.. (2008). Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate. in Acta Crystallographica Section E: Structure Reports Online
International Union of Crystallography., 64(1).
https://doi.org/10.1107/S1600536807063209
Marković R, Rašović A, Steel P. Ethyl 3-(6-phenyl-44-1,2-dithiolo[1,5-b][1,2,4]dithiazol-2-yl) propanoate. in Acta Crystallographica Section E: Structure Reports Online. 2008;64(1).
doi:10.1107/S1600536807063209 .
