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The polarographic and chronopotentiometric investigation of the copper(II)-ethylenedithioldiacetic acid system
dc.creator | Sužnjević, Desanka | |
dc.creator | Šušić, Milenko V. | |
dc.date.accessioned | 2021-06-14T18:19:05Z | |
dc.date.available | 2021-06-14T18:19:05Z | |
dc.date.issued | 1975 | |
dc.identifier.issn | 0022-0728 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/4699 | |
dc.description.abstract | The electrode process of the Cu(II)-ethylenedithioldiacetic acid chelatereduction occurs in two one-electron reduction steps. The reversibility of the first polarographic wave was confirmed by microcoulometry at constant potential. The second wave was found to be quasi-reversible unless the chelate forming agent is present in great excess. The kinetic parameters of these electrode processes were evaluated from the Koutecký and Matsuda-Ayabe theories. The value of activation energy at E=0 vs. NHE, was also found. The chronopotentiometric investigations of the same system gave resultswhich are in good agreement with those obtained polarographically. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier | sr |
dc.rights | restrictedAccess | sr |
dc.source | Journal of electroanalitical chemistry | sr |
dc.subject | polarographic and chronopotentiometric investigation | sr |
dc.subject | cooper | sr |
dc.subject | copper(II)-ethylenedithioldiacetic acid system | sr |
dc.title | The polarographic and chronopotentiometric investigation of the copper(II)-ethylenedithioldiacetic acid system | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dcterms.abstract | Шушић, Миленко В.; Сужњевић, Десанка; | |
dc.citation.volume | 61 | |
dc.citation.issue | 2 | |
dc.citation.spage | 185 | |
dc.citation.epage | 190 | |
dc.identifier.doi | 10.1016/S0022-0728(75)80249-X | |
dc.identifier.scopus | 2-s2.0-49549141430 | |
dc.type.version | publishedVersion | sr |