Synthesis and solution properties of poly(diphenyl itaconate)
Abstract
Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes.
Keywords:
Synthesis / properties of poly(diphenyl itaconate) / esterification / diphosphorus pentoxide / polymerization / AIBNSource:
European Polymer Journal, 1976, 12, 3, 151-154Publisher:
- Elsevier
Funding / projects:
- The Fund of Scientific Research of the Socialist Republic of Serbia
Collections
Institution/Community
IHTMTY - JOUR AU - Veličković, Jovan S. AU - Plavšić, Milenko B. PY - 1976 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4663 AB - Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes. PB - Elsevier T2 - European Polymer Journal T1 - Synthesis and solution properties of poly(diphenyl itaconate) VL - 12 IS - 3 SP - 151 EP - 154 DO - 10.1016/0014-3057(76)90044-6 ER -
@article{ author = "Veličković, Jovan S. and Plavšić, Milenko B.", year = "1976", abstract = "Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes.", publisher = "Elsevier", journal = "European Polymer Journal", title = "Synthesis and solution properties of poly(diphenyl itaconate)", volume = "12", number = "3", pages = "151-154", doi = "10.1016/0014-3057(76)90044-6" }
Veličković, J. S.,& Plavšić, M. B.. (1976). Synthesis and solution properties of poly(diphenyl itaconate). in European Polymer Journal Elsevier., 12(3), 151-154. https://doi.org/10.1016/0014-3057(76)90044-6
Veličković JS, Plavšić MB. Synthesis and solution properties of poly(diphenyl itaconate). in European Polymer Journal. 1976;12(3):151-154. doi:10.1016/0014-3057(76)90044-6 .
Veličković, Jovan S., Plavšić, Milenko B., "Synthesis and solution properties of poly(diphenyl itaconate)" in European Polymer Journal, 12, no. 3 (1976):151-154, https://doi.org/10.1016/0014-3057(76)90044-6 . .