Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes.
TY - JOUR
AU - Veličković, Jovan S.
AU - Plavšić, Milenko B.
PY - 1976
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4663
AB - Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes.
PB - Elsevier
T2 - European Polymer Journal
T1 - Synthesis and solution properties of poly(diphenyl itaconate)
VL - 12
IS - 3
SP - 151
EP - 154
DO - 10.1016/0014-3057(76)90044-6
ER -
@article{
author = "Veličković, Jovan S. and Plavšić, Milenko B.",
year = "1976",
abstract = "Solid diphenyl itaconate monomer was obtained by esterification in the presence of diphosphorus pentoxide and polymerized in bulk with AIBN as initiator. The non-film forming polymer powder was characterized by fractionation, viscosity measurements, light scattering and other techniques. The relation [n] = 3·6 × 10-3M0·70w, obtained for toluene at 25° was extrapolated to θ-conditions by various procedures: the σ-value of 2·60 for unperturbed dimensions indicates a less pronounced influence of phenyl compared with other C6 hydrocarbon substitutes.",
publisher = "Elsevier",
journal = "European Polymer Journal",
title = "Synthesis and solution properties of poly(diphenyl itaconate)",
volume = "12",
number = "3",
pages = "151-154",
doi = "10.1016/0014-3057(76)90044-6"
}
Veličković, J. S.,& Plavšić, M. B.. (1976). Synthesis and solution properties of poly(diphenyl itaconate). in European Polymer Journal
Elsevier., 12(3), 151-154.
https://doi.org/10.1016/0014-3057(76)90044-6
Veličković JS, Plavšić MB. Synthesis and solution properties of poly(diphenyl itaconate). in European Polymer Journal. 1976;12(3):151-154.
doi:10.1016/0014-3057(76)90044-6 .
Veličković, Jovan S., Plavšić, Milenko B., "Synthesis and solution properties of poly(diphenyl itaconate)" in European Polymer Journal, 12, no. 3 (1976):151-154,
https://doi.org/10.1016/0014-3057(76)90044-6 . .
