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dc.creatorMiodragović, D.U.
dc.creatorMitić, Dragana
dc.creatorMiodragović, Zoran
dc.creatorBogdanović, Goran A.
dc.creatorVitnik, Željko
dc.creatorVitorović, M. D.
dc.creatorRadulović, Milanka
dc.creatorNastasijević, B.J.
dc.creatorJuranić, Ivan
dc.creatorAnđelković, Katarina
dc.date.accessioned2019-01-30T17:18:42Z
dc.date.available2019-01-30T17:18:42Z
dc.date.issued2008
dc.identifier.issn0020-1693
dc.identifier.urihttp://cer.ihtm.bg.ac.rs/handle/123456789/460
dc.description.abstractFor the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH⋯π interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen.en
dc.publisherElsevier S.A.
dc.relationinfo:eu-repo/grantAgreement/MESTD/MPN2006-2010/142010/RS//
dc.rightsrestrictedAccess
dc.sourceInorganica Chimica Acta
dc.subjectCadmium(II) and Cobalt(II) complexesen
dc.subjectDFTen
dc.subjectMicrobiological assayen
dc.subjectN-Boc-glycineen
dc.subjectX-rayen
dc.subjectZinc(II)en
dc.titleSyntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complexen
dc.typearticle
dc.rights.licenseARR
dcterms.abstractМиодраговић, Д.У.; Витник, Жељко; Богдановић, Г.A.; Aнђелковић, Катарина; Јуранић, И.О.; Настасијевић, Б.Ј.; Радуловић, М.Д.; Виторовић, М.Д.; Миодраговић, З.М.; Митић, Д.М.;
dc.citation.volume361
dc.citation.issue1
dc.citation.spage86
dc.citation.epage94
dc.citation.other361(1): 86-94
dc.citation.rankM22
dc.identifier.doi10.1016/j.ica.2007.06.041
dc.identifier.rcubConv_4104
dc.identifier.scopus2-s2.0-36649002024
dc.identifier.wos000253226700012
dc.type.versionpublishedVersion


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