Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex
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2008
Authors
Miodragović, D.U.Mitić, Dragana

Miodragović, Zoran
Bogdanović, Goran A.

Vitnik, Željko

Vitorović, Maja D.

Radulović, Milanka

Nastasijević, Branislav
Juranić, Ivan

Anđelković, Katarina

Article (Published version)

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For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH⋯π interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen.
Keywords:
Cadmium(II) and Cobalt(II) complexes / DFT / Microbiological assay / N-Boc-glycine / X-ray / Zinc(II)Source:
Inorganica Chimica Acta, 2008, 361, 1, 86-94Publisher:
- Elsevier S.A.
Funding / projects:
DOI: 10.1016/j.ica.2007.06.041
ISSN: 0020-1693
WoS: 000253226700012
Scopus: 2-s2.0-36649002024
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IHTMTY - JOUR AU - Miodragović, D.U. AU - Mitić, Dragana AU - Miodragović, Zoran AU - Bogdanović, Goran A. AU - Vitnik, Željko AU - Vitorović, Maja D. AU - Radulović, Milanka AU - Nastasijević, Branislav AU - Juranić, Ivan AU - Anđelković, Katarina PY - 2008 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/460 AB - For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH⋯π interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. PB - Elsevier S.A. T2 - Inorganica Chimica Acta T1 - Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex VL - 361 IS - 1 SP - 86 EP - 94 DO - 10.1016/j.ica.2007.06.041 ER -
@article{ author = "Miodragović, D.U. and Mitić, Dragana and Miodragović, Zoran and Bogdanović, Goran A. and Vitnik, Željko and Vitorović, Maja D. and Radulović, Milanka and Nastasijević, Branislav and Juranić, Ivan and Anđelković, Katarina", year = "2008", abstract = "For the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH⋯π interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen.", publisher = "Elsevier S.A.", journal = "Inorganica Chimica Acta", title = "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex", volume = "361", number = "1", pages = "86-94", doi = "10.1016/j.ica.2007.06.041" }
Miodragović, D.U., Mitić, D., Miodragović, Z., Bogdanović, G. A., Vitnik, Ž., Vitorović, M. D., Radulović, M., Nastasijević, B., Juranić, I.,& Anđelković, K.. (2008). Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex. in Inorganica Chimica Acta Elsevier S.A.., 361(1), 86-94. https://doi.org/10.1016/j.ica.2007.06.041
Miodragović D, Mitić D, Miodragović Z, Bogdanović GA, Vitnik Ž, Vitorović MD, Radulović M, Nastasijević B, Juranić I, Anđelković K. Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex. in Inorganica Chimica Acta. 2008;361(1):86-94. doi:10.1016/j.ica.2007.06.041 .
Miodragović, D.U., Mitić, Dragana, Miodragović, Zoran, Bogdanović, Goran A., Vitnik, Željko, Vitorović, Maja D., Radulović, Milanka, Nastasijević, Branislav, Juranić, Ivan, Anđelković, Katarina, "Syntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine. X-ray crystal structure of the polymeric Cd(II) complex" in Inorganica Chimica Acta, 361, no. 1 (2008):86-94, https://doi.org/10.1016/j.ica.2007.06.041 . .