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dc.creatorMihailović, Milhailo Lj.
dc.creatorMilosavljević, Slobodan
dc.creatorJeremić, Dragoslav
dc.creatorMilovanović, Jovan N.
dc.date.accessioned2021-05-07T08:55:10Z
dc.date.available2021-05-07T08:55:10Z
dc.date.issued1977
dc.identifier.issn0030-4921
dc.identifier.issn1097-458X
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4549
dc.description.abstractThe configurational and conformational relationship at C‐2 and C‐α in the two racemic diastereomeric endo‐α‐methyl‐5‐norbornene‐2‐methanols and the corresponding saturated endo‐α‐methyl‐2‐norbornanemethanols were determined by first‐order analysis of the 1H n.m.r. spectra of these compounds and of their cyclization ether products, i.e. 3‐methyl‐2‐oxatricyclo[4.2.1.04,8]nonanes and 5‐methyl‐4‐oxatricyclo[4.3.0.03,8]nonanes. In addition, the conformational preference of the hydroxyl group in the unsaturated and saturated alcohols was confirmed by the lanthanide induced shift technique, using Eu(fod)3 as shift reagent, combined with a computer program involving various conformations of the –CHOHMe group.sr
dc.language.isoensr
dc.publisherWileysr
dc.rightsrestrictedAccesssr
dc.sourceOrganic Magnetic Resonancesr
dc.subjectH n.m.r. spectrasr
dc.subjectbicyclic compoundssr
dc.subjectcyclization ether productssr
dc.subjectunsaturated and saturated alcoholssr
dc.subjectNMR spectrometrysr
dc.title1H n.m.r. spectra of some bicyclic compounds: I—relative configurations of the diastereomeric endo‐α‐methyl‐5‐norbornene‐2‐methanols, the corresponding saturated analogues, and their cyclization ether productssr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractМиловановић, Јован Н.; Милосављевић, Слободан; Михаиловић, Михаило Љ.; Јеремић, Драгослав;
dc.citation.volume9
dc.citation.issue4
dc.citation.spage229
dc.citation.epage234
dc.identifier.doi10.1002/mrc.1270090411
dc.identifier.scopus2-s2.0-84986734481
dc.type.versionpublishedVersionsr


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