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dc.creatorVraneš, Milan B.
dc.creatorRadović, Ivona
dc.creatorBikić, Siniša M.
dc.creatorTot, Aleksandar
dc.creatorKijevčanin, Mirjana
dc.creatorZarić, Milana
dc.creatorBorović, Teona Teodora
dc.creatorPapović, Snežana
dc.date.accessioned2021-04-21T12:51:29Z
dc.date.available2021-04-21T12:51:29Z
dc.date.issued2021
dc.identifier.issn0167-7322
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4485
dc.description.abstractIn this article, detailed physicochemical characterization of ethylene glycol and caffeine + ethylene glycol mixtures is performed based on density, viscosity and refractive indices measurements in temperature range from (288.15 to 343.15) K. The apparent molar volume (Vϕ), apparent molar volume at infinite dilution (Vϕo), Masson's experimental slope (Sv), limiting apparent molar expansibility, (Eϕo), viscosity B-coefficient, thermodynamical parameters of viscous flow and molar refractions (Rm) have been evaluated from experimental measurements and results are additionally proven by molecular dynamic simulations. The addition of caffeine reduces viscosity of ethylene glycol, while caffeine molecules have high tendency to form self-aggregates due to weak interactions with ethylene glycol. Compared to aqueous solution of caffeine, caffeine + ethylene glycol mixtures are characterized with significantly lower solvation number and with more pronounced caffeine self-aggregation.sr
dc.language.isoensr
dc.publisherElseviersr
dc.relationinfo:eu-repo/grantAgreement/ScienceFundRS/Promis/6066818/RS//sr
dc.relation.isreferencedbyhttps://cer.ihtm.bg.ac.rs/handle/123456789/4486
dc.rightsrestrictedAccesssr
dc.sourceJournal of Molecular Liquidssr
dc.subjectCaffeinesr
dc.subjectDensitysr
dc.subjectEthylene glycolsr
dc.subjectRefractive indexsr
dc.subjectTransport fluidsr
dc.subjectViscositysr
dc.titleImproving ethylene glycol transport properties by caffeine – Thermodynamic and computational evidencesr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractКијевчанин, Мирјана; Вранеш, Милан Б.; Радовић, Ивона; Бикић, Синиша М.; Тот, Aлександар С.; Зарић, Милана М.; Паповић, Снежана М.; Боровић, Теона Теодора;
dc.citation.volume333
dc.citation.issue0167-7322
dc.citation.issue1873-3166
dc.citation.spage115918
dc.citation.rankM21~
dc.description.otherSupplementary data: [https://cer.ihtm.bg.ac.rs/handle/123456789/4486]
dc.identifier.doi10.1016/j.molliq.2021.115918
dc.identifier.scopus2-s2.0-85102976381
dc.identifier.wos000648674100028
dc.type.versionpublishedVersionsr


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Приказ основних података о документу