Multistage alkaline permanganate degradation of a type II kerogen
Samo za registrovane korisnike
1984
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration.
Ključne reči:
oil shale / organic compounds / dicarboxylic acids / acids / chemical reactions-oxidation / toarcian shale / monocarboxylic acids / tricarboxylic acidsIzvor:
Organic Geochemistry, 1984, 5, 4, 259-265Izdavač:
- Elsevier
Finansiranje / projekti:
- The Research Fund of SR Serbia, Yugoslavia
Institucija/grupa
IHTMTY - JOUR AU - Vitorović, Dragomir K. AU - Đorđević, Mirjana V. AU - Amblès, André AU - Jacquesy, Jean Claude PY - 1984 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4476 AB - The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration. PB - Elsevier T2 - Organic Geochemistry T1 - Multistage alkaline permanganate degradation of a type II kerogen VL - 5 IS - 4 SP - 259 EP - 265 DO - 10.1016/0146-6380(84)90013-5 ER -
@article{ author = "Vitorović, Dragomir K. and Đorđević, Mirjana V. and Amblès, André and Jacquesy, Jean Claude", year = "1984", abstract = "The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration.", publisher = "Elsevier", journal = "Organic Geochemistry", title = "Multistage alkaline permanganate degradation of a type II kerogen", volume = "5", number = "4", pages = "259-265", doi = "10.1016/0146-6380(84)90013-5" }
Vitorović, D. K., Đorđević, M. V., Amblès, A.,& Jacquesy, J. C.. (1984). Multistage alkaline permanganate degradation of a type II kerogen. in Organic Geochemistry Elsevier., 5(4), 259-265. https://doi.org/10.1016/0146-6380(84)90013-5
Vitorović DK, Đorđević MV, Amblès A, Jacquesy JC. Multistage alkaline permanganate degradation of a type II kerogen. in Organic Geochemistry. 1984;5(4):259-265. doi:10.1016/0146-6380(84)90013-5 .
Vitorović, Dragomir K., Đorđević, Mirjana V., Amblès, André, Jacquesy, Jean Claude, "Multistage alkaline permanganate degradation of a type II kerogen" in Organic Geochemistry, 5, no. 4 (1984):259-265, https://doi.org/10.1016/0146-6380(84)90013-5 . .