The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration.
TY - JOUR
AU - Vitorović, Dragomir K.
AU - Đorđević, Mirjana V.
AU - Amblès, André
AU - Jacquesy, Jean Claude
PY - 1984
UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4476
AB - The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration.
PB - Elsevier
T2 - Organic Geochemistry
T1 - Multistage alkaline permanganate degradation of a type II kerogen
VL - 5
IS - 4
SP - 259
EP - 265
DO - 10.1016/0146-6380(84)90013-5
ER -
@article{
author = "Vitorović, Dragomir K. and Đorđević, Mirjana V. and Amblès, André and Jacquesy, Jean Claude",
year = "1984",
abstract = "The products of a 27-step alkaline permanganate degradation of a type II kerogen from a sample of Toarcian shale, Paris Basin, have been studied. The high yield of oxidation products consisted of 1.86% neutrals and bases, 24.48% ether-soluble acids, and 45.95% precipitated, ether-insoluble acids, based on weight of original kerogen. The ether-soluble acids and the soluble products of further permanganate degradation of precipitated acids were found to consist mostly of saturated unbranched C6-C22 α,ω-dicarboxylic and C9-C25 monocarboxylic acids. Significant amounts of aromatic monocarboxylic, dicarboxylic and tricarboxylic acids were also found. Alkane tri- and tetracarboxylic acids were obtained in small concentration.",
publisher = "Elsevier",
journal = "Organic Geochemistry",
title = "Multistage alkaline permanganate degradation of a type II kerogen",
volume = "5",
number = "4",
pages = "259-265",
doi = "10.1016/0146-6380(84)90013-5"
}
Vitorović, D. K., Đorđević, M. V., Amblès, A.,& Jacquesy, J. C.. (1984). Multistage alkaline permanganate degradation of a type II kerogen. in Organic Geochemistry
Elsevier., 5(4), 259-265.
https://doi.org/10.1016/0146-6380(84)90013-5
Vitorović DK, Đorđević MV, Amblès A, Jacquesy JC. Multistage alkaline permanganate degradation of a type II kerogen. in Organic Geochemistry. 1984;5(4):259-265.
doi:10.1016/0146-6380(84)90013-5 .
Vitorović, Dragomir K., Đorđević, Mirjana V., Amblès, André, Jacquesy, Jean Claude, "Multistage alkaline permanganate degradation of a type II kerogen" in Organic Geochemistry, 5, no. 4 (1984):259-265,
https://doi.org/10.1016/0146-6380(84)90013-5 . .
