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Determination of glass temperature of polymers by inverse gas chromatography

Authorized Users Only
2008
Authors
Nastasović, Aleksandra
Onjia, Antonije E.
Article (Published version)
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Abstract
Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (Tg) measurements.
Keywords:
IGC / Polymer-solvent interactions / Retention mechanism / Thermal transitions / Z-shaped retention diagram
Source:
Journal of Chromatography A, 2008, 1195, 1-2, 1-15
Publisher:
  • Elsevier
Funding / projects:
  • Nove metode i tehnike za separaciju i specijaciju hemijskih elemenata u tragovima, organskih supstanci i radionuklida i identifikaciju njihovih izvora (RS-142039)

DOI: 10.1016/j.chroma.2008.05.009

ISSN: 0021-9673

PubMed: 18501369

WoS: 000257258800001

Scopus: 2-s2.0-44749087324
[ Google Scholar ]
42
39
URI
https://cer.ihtm.bg.ac.rs/handle/123456789/445
Collections
  • Radovi istraživača / Researchers' publications
Institution/Community
IHTM
TY  - JOUR
AU  - Nastasović, Aleksandra
AU  - Onjia, Antonije E.
PY  - 2008
UR  - https://cer.ihtm.bg.ac.rs/handle/123456789/445
AB  - Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (Tg) measurements.
PB  - Elsevier
T2  - Journal of Chromatography A
T1  - Determination of glass temperature of polymers by inverse gas chromatography
VL  - 1195
IS  - 1-2
SP  - 1
EP  - 15
DO  - 10.1016/j.chroma.2008.05.009
ER  - 
@article{
author = "Nastasović, Aleksandra and Onjia, Antonije E.",
year = "2008",
abstract = "Inverse gas chromatography (IGC) is an attractive technique for polymer characterization due to possible simultaneous determination of various physicochemical properties of polymer systems merely from retention times of selected sorbates. The technique is especially advantageous to polymers that cannot be characterized by conventional methods. In this review, the utilization of the method for glass transition determination of homopolymers, copolymers and polymer blends is described. Advantages and drawbacks of the IGC method over traditionally used methods for glass transition temperature determination is discussed, along with the most important parameters that influence the precision and accuracy of the glass transition temperature (Tg) measurements.",
publisher = "Elsevier",
journal = "Journal of Chromatography A",
title = "Determination of glass temperature of polymers by inverse gas chromatography",
volume = "1195",
number = "1-2",
pages = "1-15",
doi = "10.1016/j.chroma.2008.05.009"
}
Nastasović, A.,& Onjia, A. E.. (2008). Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A
Elsevier., 1195(1-2), 1-15.
https://doi.org/10.1016/j.chroma.2008.05.009
Nastasović A, Onjia AE. Determination of glass temperature of polymers by inverse gas chromatography. in Journal of Chromatography A. 2008;1195(1-2):1-15.
doi:10.1016/j.chroma.2008.05.009 .
Nastasović, Aleksandra, Onjia, Antonije E., "Determination of glass temperature of polymers by inverse gas chromatography" in Journal of Chromatography A, 1195, no. 1-2 (2008):1-15,
https://doi.org/10.1016/j.chroma.2008.05.009 . .

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