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dc.creatorSpasojević, Miroslav D.
dc.creatorKrstajić, Nedeljko V.
dc.creatorJakšić, Milan M.
dc.date.accessioned2021-04-13T06:02:52Z
dc.date.available2021-04-13T06:02:52Z
dc.date.issued1984
dc.identifier.issn0376-4583
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4434
dc.description.abstractIt has been shown that while the mixed RuO2TiO2 coated titanium anode deteriorates very quickly in the presence of ionic phosphate species, the electrode containing palladium and tin oxides in the coating mixture as well as the former catalyst exhibits almost equal electrocatalytic activity and a high corrosion stability in both dichromate and phosphate buffering systems. Electrocatalytic optimization of faradaic yields over a much wider pH range for the chlorate cell process has been achieved by the mixed ruthenium, palladium, tin and titanium oxide catalysts and in the presence of a phosphate buffer. The effect is tentatively ascribed to the phosphate adsorption associated with further activation polarization (inhibition effect) of the available chlorine oxidation reaction at the anode. Two benefits result therefrom: (a) the pH value can be kept at around pH 7, providing better elemental chlorine absorption, and (b) dichromate buffer can be at least partially replaced by the more convinient phosphate buffering system.sr
dc.language.isoensr
dc.publisherElseviersr
dc.rightsrestrictedAccesssr
dc.sourceSurface Technologysr
dc.subjectchlorate cellsr
dc.subjectfaradaic yieldssr
dc.subjectcoated titanium anodesr
dc.subjectElectrocatalysissr
dc.titleElectrocatalytic optimization of faradaic yields in the chlorate cell processsr
dc.typearticlesr
dc.rights.licenseARRsr
dcterms.abstractЈакшић, Милан М.; Крстајић, Недељко В.; Спасојевић, Мирослав Д.;
dc.citation.volume21
dc.citation.issue1
dc.citation.spage19
dc.citation.epage26
dc.identifier.doi10.1016/0376-4583(84)90144-4
dc.identifier.scopus2-s2.0-0021157135
dc.type.versionpublishedVersionsr


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Приказ основних података о документу