Show simple item record

dc.creatorKošević, Milica G.
dc.creatorZarić, Milana M.
dc.creatorStopić, Srećko R.
dc.creatorStevanović, Jasmina S.
dc.creatorWeirich, Thomas E.
dc.creatorFriedrich, B.
dc.creatorPanić, Vladimir V.
dc.date.accessioned2021-04-09T10:06:23Z
dc.date.available2021-04-09T10:06:23Z
dc.date.issued2020
dc.identifier.issn2075-4701
dc.identifier.urihttps://cer.ihtm.bg.ac.rs/handle/123456789/4430
dc.description.abstractPt/TiO2 composites were synthesized by single-step ultrasonic spray pyrolysis (USP) at different temperatures. In an in-situ method, Pt and TiO2 particles were generated from tetra-n-butyl orthotitanate and chloroplatinic acid, and hydrothermally-prepared TiO2 colloidal dispersion served as Pt support in an ex-situ USP approach. USP-synthesized Pt/TiO2 composites were generated in the form of a solid mixture, morphologically organized in nesting huge hollow and small solid spheres, or TiO2 core/Pt shell regular spheroids by in-situ or ex-situ method, respectively. This paper exclusively reports on characteristic mechanisms of the formation of novel two-component solid composites, which are intrinsic from the USP approach and controlled precursor composition. The generation of the two morphological components within the in-situ approach, the hollow spheres and all-solid spheres, was indicated to be caused by characteristic sol-gel/solid phase transition of TiO2 . Both the walls of the hollow spheres and the cores of all-solid ones consist of TiO2 matrix populated by 10 nm-sized Pt. On the other hand, spherical, uniformly-sized, Pt particles of a few nanometers in size created a shell uniformly deposited onto TiO2 spheres of ca. 150 nm size. Activities of the prepared samples in an oxygen reduction reaction and combined oxygen reduction and hydrogen evolution reactions were electrochemically tested. The ex-situ synthesized Pt/TiO2 was more active for oxygen reduction and combined oxygen reduction and hydrogen reactions in comparison to the in-situ Pt/TiO2 samples, due to better availability of Pt within a core/shell structure for the reactions.sr
dc.language.isoensr
dc.publisherSwitzerland : Multidisciplinary Digital Publishing Institute (MDPI)sr
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172060/RS//sr
dc.relationThe German Academic Exchange Service DAAD ( project No. 57334757)sr
dc.rightsopenAccesssr
dc.sourceMetalssr
dc.subjectElectrocatalysissr
dc.subjectPt/TiO2 synthesissr
dc.subjectSupported Pt nanoparticlessr
dc.subjectTitanium oxide colloidsr
dc.titleStructural and electrochemical properties of nesting and core/shell pt/tio2 spherical particles synthesized by ultrasonic spray pyrolysissr
dc.typearticlesr
dc.rights.licenseBYsr
dcterms.abstractПанић, Владимир В.; Фриедрицх, Б.; Wеирицх, Тхомас Е.; Стевановић, Јасмина С.; Стопић, Срећко Р.; Кошевић, Милица Г.; Зарић, Милана М.;
dc.citation.volume10
dc.citation.issue1
dc.citation.spage11
dc.citation.rankM21~
dc.identifier.doi10.3390/met10010011
dc.identifier.fulltexthttp://cer.ihtm.bg.ac.rs/bitstream/id/19771/metals-10-00011.pdf
dc.identifier.scopus2-s2.0-85077373351
dc.identifier.wos000516827800011
dc.type.versionpublishedVersionsr


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record