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Ferrous ion induced decomposition of alkyl hypochlorites
dc.creator | Čeković, Živorad | |
dc.creator | Đokić, Gordana | |
dc.date.accessioned | 2021-04-06T06:05:46Z | |
dc.date.available | 2021-04-06T06:05:46Z | |
dc.date.issued | 1981 | |
dc.identifier.issn | 0040-4020 | |
dc.identifier.issn | 1464-5416 | |
dc.identifier.uri | https://cer.ihtm.bg.ac.rs/handle/123456789/4418 | |
dc.description.abstract | The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76%. In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination. Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ω-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction. | sr |
dc.language.iso | en | sr |
dc.publisher | Elsevier | sr |
dc.rights | restrictedAccess | sr |
dc.source | Tetrahedron | sr |
dc.subject | alkyl hypochlorites | sr |
dc.subject | Ferrous ion | sr |
dc.subject | one-electron oxidation | sr |
dc.subject | β-fragmentation | sr |
dc.subject | chkoro-alcihols | sr |
dc.subject | δ-chlorination | sr |
dc.title | Ferrous ion induced decomposition of alkyl hypochlorites | sr |
dc.type | article | sr |
dc.rights.license | ARR | sr |
dcterms.abstract | Ђокић, Гордана; Чековић, Живорад М.; | |
dc.citation.volume | 37 | |
dc.citation.issue | 24 | |
dc.citation.spage | 4263 | |
dc.citation.epage | 4268 | |
dc.identifier.doi | 10.1016/0040-4020(81)85021-1 | |
dc.identifier.scopus | 2-s2.0-0013530809 | |
dc.type.version | publishedVersion | sr |