Ferrous ion induced decomposition of alkyl hypochlorites
Само за регистроване кориснике
1981
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76%. In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination. Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ω-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction.
Кључне речи:
alkyl hypochlorites / Ferrous ion / one-electron oxidation / β-fragmentation / chkoro-alcihols / δ-chlorinationИзвор:
Tetrahedron, 1981, 37, 24, 4263-4268Издавач:
- Elsevier
DOI: 10.1016/0040-4020(81)85021-1
ISSN: 0040-4020; 1464-5416
Scopus: 2-s2.0-0013530809
Институција/група
IHTMTY - JOUR AU - Čeković, Živorad AU - Đokić, Gordana PY - 1981 UR - https://cer.ihtm.bg.ac.rs/handle/123456789/4418 AB - The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76%. In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination. Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ω-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction. PB - Elsevier T2 - Tetrahedron T1 - Ferrous ion induced decomposition of alkyl hypochlorites VL - 37 IS - 24 SP - 4263 EP - 4268 DO - 10.1016/0040-4020(81)85021-1 ER -
@article{ author = "Čeković, Živorad and Đokić, Gordana", year = "1981", abstract = "The decomposition of primary, secondary and tertiary alkyl hypochlorites induced by ferrous and other one-electron oxidizable metal ions leads to δ-chloro alcohols in yields of 34-76%. In decomposition of tertiary alkyl hypochlorites, β-fragmentation competes with intramolecular δ-chlorination. Tertiary cycloalkyl hypochlorites containing five- or six-membered rings undergo β-cleavage giving the corresponding ω-chloro ketones, while 1-methylcycloheptyl and 1-methylcyclooctyl hypochlorites by decomposition with ferrous ion proceed by transannular functionalization of δ-carbon atom and β-cleavage as a competing reaction.", publisher = "Elsevier", journal = "Tetrahedron", title = "Ferrous ion induced decomposition of alkyl hypochlorites", volume = "37", number = "24", pages = "4263-4268", doi = "10.1016/0040-4020(81)85021-1" }
Čeković, Ž.,& Đokić, G.. (1981). Ferrous ion induced decomposition of alkyl hypochlorites. in Tetrahedron Elsevier., 37(24), 4263-4268. https://doi.org/10.1016/0040-4020(81)85021-1
Čeković Ž, Đokić G. Ferrous ion induced decomposition of alkyl hypochlorites. in Tetrahedron. 1981;37(24):4263-4268. doi:10.1016/0040-4020(81)85021-1 .
Čeković, Živorad, Đokić, Gordana, "Ferrous ion induced decomposition of alkyl hypochlorites" in Tetrahedron, 37, no. 24 (1981):4263-4268, https://doi.org/10.1016/0040-4020(81)85021-1 . .